Radiation-Curable Coating Composition for Composite Substrates

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Solution Overview

Problem

Existing coatings for composite substrates such as cementitious composites, plastic composites, ceramic composites, and engineered woods lack durability, adhesion, and aesthetic appeal, particularly under varying temperature, moisture, and sunlight exposure.

Innovation Solution

A radiation-curable coating composition comprising a multifunctional oligomer, monomers, a photoinitiator, a polyester resin, and a polycarboxylic acid, which is applied and cured using actinic radiation, providing enhanced adhesion and resistance to abrasion, marring, and maintaining an aesthetically pleasing appearance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional coatings are applied to composite substrates, then the coating can be applied and cured, but the coating lacks durability, adhesion, and aesthetic appeal under varying environmental conditions

Engineering Contradiction:
Improvecoating durability and adhesionVSAvoidresistance to environmental factors
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the chemical composition parameters of the coating by incorporating specific ratios of oligomers (30-70 wt%), monomers (20-50 wt%), polyester resins (5-20 wt%), and polycarboxylic acids (1-10 wt%). This compositional parameter change enables the coating to achieve both durability and resistance to environmental factors including temperature variations, moisture, and UV exposure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite coating system by combining multiple chemical components with complementary properties: oligomers provide adhesion and flexibility, monomers ensure complete curing and hardness, polyester resins enhance durability, and polycarboxylic acids improve weatherability. This composite material approach resolves the contradiction by integrating functions that individually would be insufficient.

Inventive Principle:
Principle #40Composite materials

2Productivity

If radiation-curable coating composition is used, then the coating cures quickly suitable for high-speed manufacturing, but the composition complexity increases

Engineering Contradiction:
Improvecuring speedVSAvoidcoating composition complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent replaces traditional thermal curing mechanisms with photopolymerization initiated by actinic radiation. This substitution enables rapid curing suitable for high-speed manufacturing while the carefully controlled composition (specific component ratios and molecular weights) manages the complexity by ensuring predictable and consistent curing behavior.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent incorporates photoinitiators in predetermined amounts (0.1-5 wt%) that are pre-selected to match the specific actinic radiation source intended for curing. This preliminary action ensures that the coating composition is optimized for its intended curing method, allowing rapid curing without excessive complexity in the formulation process.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating composition adheres well to composite substrates, resists environmental factors, and is suitable for high-speed manufacturing, offering improved durability and appearance retention.

Implementation Method 1

a radiation curable coating composition... a photoinitiator... curing the coating composition by exposing the curable coating to radiation

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS8440013B2Radiation-curable coating compositions, composite and plastic materials coated with said compositions and methods for their preparation
Publication Date: 2013.05.14 FINISHES UNLTD

AI summary

Disclosed is a curable coating composition suitable for use on composite substrates such as plastic composites, cementitious composites, ceramic composites, and engineered wood, or on plastic materials. The curable coating composition comprises a multifunctional oligomer, a monomer selected from the group consisting of monofunctional monomers, difunctional monomers and mixtures thereof, a photoinitiator, a polyester resin and a polycarboxylic acid. Also disclosed is a method of coating the substrates with the curable coating composition and a coated substrate wherein the cured coating resides on the surface of the substrate.