Radiation Curable Ink for Low Temperature Jetting

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Solution Overview

Problem

Existing curable phase change inks used in ink jet printing require high temperatures for jetting, which limits the robustness and lower temperature operation of printed images, and there is a need for improved image formation methods that reduce showthrough and enhance image quality.

Innovation Solution

A radiation curable ink comprising a liquid curable monomer, a curable wax, and a colorant, with a photoinitiator that initiates polymerization upon exposure to radiation, allowing for lower temperature jetting and improved image formation by controlling viscosity and curing process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If high temperature jetting is used for curable phase change inks, then the ink viscosity is reduced for proper jetting, but the operational temperature must be increased which limits image robustness and increases energy consumption

Engineering Contradiction:
Improvejetting temperatureVSAvoidenergy consumption
Core Design Contradiction:
TemperatureVSLoss of energy

Solution Approach 1:

The patent changes the chemical composition parameters of the ink by incorporating radiation-curable components (acrylates, epoxides, vinyl compounds) alongside the phase change wax. This compositional parameter change allows the ink to cure at lower temperatures through radiation-induced polymerization, eliminating the need for high temperature maintenance and reducing energy consumption while improving image robustness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the thermal curing mechanism (heat-based) with a radiation-based curing mechanism. Instead of relying solely on high temperature to maintain ink in liquid state and then cooling for solidification, the invention uses radiation (UV or electron beam) to initiate polymerization of curable components, substituting thermal energy with electromagnetic energy for the curing process, thereby reducing operational temperature and energy consumption.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Temperature

If high temperature jetting is used for curable phase change inks, then the ink remains liquid for ejection, but the image robustness and stability are reduced due to higher operational temperatures

Engineering Contradiction:
Improveoperating temperatureVSAvoidimage robustness
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent replaces thermal curing with radiation-induced polymerization. The curable components (acrylates, epoxides, vinyl compounds) undergo rapid polymerization upon radiation exposure, forming crosslinked networks that provide superior image robustness and stability at lower operating temperatures, eliminating the trade-off between temperature and image quality.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent creates a composite ink formulation combining phase change waxes with radiation-curable monomers and oligomers. This composite material system leverages both the phase change properties for jetting control and the polymerization properties for image stabilization, achieving robust images at lower temperatures through synergistic material combination.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If conventional curable inks are used, then image formation requires high temperature operation, but this increases showthrough and reduces image quality

Engineering Contradiction:
Improveimage qualityVSAvoidshowthrough
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent changes the curing mechanism parameter from thermal to radiation-based. The radiation-curable components polymerize rapidly upon exposure to UV or electron beam radiation, forming stable images at lower temperatures that reduce showthrough and improve image quality, directly addressing the harmful effects of high temperature operation.

Inventive Principle:
Principle #35Parameter changes

4Temperature

If radiation curable components are added to the ink, then polymerization can occur at lower temperatures, but the ink formulation complexity increases

Engineering Contradiction:
Improvecuring temperatureVSAvoidink formulation complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The patent employs radiation-curable components that serve multiple functions: they act as both the liquid vehicle for ink jetting and the curable matrix for image formation. The acrylates, epoxides, and vinyl compounds provide both flow properties during jetting and crosslinked structure after curing, reducing the need for separate additives and simplifying the overall formulation despite the advanced chemistry.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The radiation curable ink enables robust image formation with reduced showthrough and enhanced quality by polymerizing the curable components at lower temperatures, improving the operational efficiency and image stability in ink jet printing systems.

Implementation Method 1

an initiator, preferably a photoinitiator, that initiates polymerization of curable components of the ink upon exposure to radiation

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

radiation curable phase change inks that can be used in ink jet printing

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentUS7559639B2Radiation curable ink containing a curable wax
Publication Date: 2009.07.14 XEROX CORP
  • US7559639B2 patent drawing
  • US7559639B2 patent drawing
  • US7559639B2 patent drawing

AI summary

Curable monomer that is liquid at 25° C., curable wax and colorant together from a radiation curable ink. This ink may be used to form images by providing the radiation curable ink at a first temperature; applying the radiation curable ink to the substrate to form an image, the substrate being at a second temperature, which is below the first temperature; and exposing the radiation curable ink to radiation to cure the ink.