Radiation Polymerizable Composition for Optical Fiber Primary Coating
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Solution Overview
Problem
Existing radiation curable resin compositions for optical fiber primary coating layers have a curing rate that is not sufficiently fast to further improve the productivity of optical fiber production.
Innovation Solution
A radiation polymerizable composition comprising a urethane oligomer with a specific structure, one or more compounds such as maleic anhydride, and a radiation polymerization initiator, which together enhance the curing rate by irradiation.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Speed
If a conventional radiation curable resin composition comprising a urethane oligomer and a monofunctional acrylic monomer is used, then the primary coating layer can be formed with flexibility, but the curing rate by irradiation is not sufficiently fast
Solution Approach 1:
The patent changes the chemical structure parameters of the urethane oligomer by introducing vinyl groups at terminal positions and incorporating maleimide structures. These parameter changes enable the oligomer to undergo rapid photopolymerization while maintaining the flexibility required for optical fiber primary coating layers, thus resolving the contradiction between curing rate and flexibility.
Solution Approach 2:
The patent creates a composite resin composition by combining specifically structured vinyl-containing urethane oligomers with maleimide compounds and photopolymerization initiators. This composite material achieves both fast curing rate through the maleimide-enhanced polymerization and maintained flexibility through the urethane oligomer's molecular structure with terminal vinyl groups.
2Productivity
If the curing rate is increased to improve productivity, then the production efficiency improves, but the flexibility of the primary coating layer may be compromised
Solution Approach 1:
By modifying the urethane oligomer structure to include terminal vinyl groups and maleimide moieties, the patent enables faster photopolymerization kinetics without sacrificing the elastic properties needed for flexibility. This parameter change allows high-speed curing that improves productivity while preserving the coating layer's ability to protect the optical fiber.
Solution Approach 2:
The maleimide compound acts as an intermediary that accelerates the photopolymerization process. It facilitates rapid crosslinking of the vinyl groups on the urethane oligomer, enabling fast curing for improved productivity while the urethane oligomer's base structure maintains the flexibility required for ease of operation.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composition achieves a faster curing rate, allowing for higher productivity in optical fiber production while maintaining the necessary flexibility of the cured layer.
Implementation Method 1
a radiation polymerizable composition for forming a primary coating layer of an optical fiber, the radiation polymerizable composition comprising: (A) a urethane oligomer comprising a structure represented by formula (I) below: wherein R is a vinyl group and * is a bond; (B) one or more compounds of: (i) maleic anhydride; (ii) a compound represented by formula (II) below...
Data Source
AI summary
[Problem] To provide a radiation curable resin composition that is suitable as a primary material of an optical fiber and has a fast curing rate by irradiation with radiation. [Solution] A radiation polymerizable composition for forming a primary coating layer of an optical fiber, the radiation polymerizable composition comprising: (A) a urethane oligomer comprising a structure represented by formula (I) below: wherein R is a vinyl group and * is a bond; (B) one or more compounds of: (i) maleic anhydride, (ii) a compound represented by formula (II): wherein R1 is a single bond or an alkanediyl group comprising 1 to 6 carbon atoms, and R2 is a hydrogen atom, a hydroxy group, or a group represented by predetermined formula (II-1) or formula (II-2), or (iii) a compound represented by formula (III): wherein R5 is an alkanediyl group comprising 1 to 6 carbon atoms; and (C) a radiation polymerization initiator.


