Radical Compound Marking Composition for Hydrocarbon Traceability

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Solution Overview

Problem

Current methods for marking hydrocarbon compositions to determine origin and trace manufacturing processes are cumbersome, requiring laboratory analysis on sophisticated devices, making it difficult to quickly and simply identify counterfeit products or ensure quality on-site.

Innovation Solution

Incorporating a radical compound detectable by Electronic Paramagnetic Resonance (EPR) into hydrocarbon compositions or additive compositions, allowing for rapid on-site detection using portable EPR devices, thereby tracing the origin and quality of hydrocarbon compositions, including those with water and urea used in the automotive field.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional marking compounds are used for detecting origin of hydrocarbon compositions, then the marking can be detected by laboratory analysis, but the analysis requires sophisticated equipment and cannot be performed quickly on site

Engineering Contradiction:
Improvedetection capabilityVSAvoidequipment complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent replaces conventional laboratory analytical methods with EPR (Electron Paramagnetic Resonance) spectroscopy, which is a physical detection method based on magnetic resonance. This substitution enables detection without complex chemical analysis equipment, allowing portable devices to be used on-site while maintaining detection precision through the specific magnetic resonance signal of the radical compound marker.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the detection parameter from general chemical analysis to specific magnetic resonance signal detection. By using a radical compound marker with unpaired electrons, the system exploits the unique EPR signal characteristics (g-factor, hyperfine coupling) to identify the marker, enabling selective and sensitive detection with simplified equipment compared to broad-spectrum laboratory analysis.

Inventive Principle:
Principle #35Parameter changes

2Loss of information

If conventional marking compounds are used for tracing manufacturing processes, then the origin can be determined by laboratory analysis, but the process cannot be traced quickly and the quality control is time-consuming

Engineering Contradiction:
Improvetraceability informationVSAvoidanalysis time
Core Design Contradiction:
Loss of informationVSLoss of time

Solution Approach 1:

The radical compound marker is incorporated into the hydrocarbon composition during the manufacturing process itself, serving as a pre-installed traceable identifier. This preliminary action embeds the tracking information directly in the product, eliminating the need for subsequent complex analysis to determine origin or batch information, thus enabling rapid quality control and traceability verification.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces time-consuming laboratory chromatography or spectroscopy methods with rapid EPR detection. The EPR technique provides quick identification of the radical compound marker, enabling fast traceability verification and quality control decisions to be made on-site without lengthy analytical procedures.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Measurement precision

If marking compounds requiring laboratory analysis are used, then accurate detection is possible, but portable on-site detection cannot be achieved

Engineering Contradiction:
Improvedetection accuracyVSAvoidon-site detection capability
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The invention substitutes complex laboratory analytical systems with a portable EPR spectrometer system. The EPR detection method, based on magnetic resonance of unpaired electrons in the radical compound, can be implemented in a compact, portable device that maintains laboratory-level detection accuracy while enabling field operations. The specific magnetic resonance signal provides unambiguous identification of the marker.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The radical compound marker serves multiple functions: it provides a detectable signal for origin identification, enables batch tracing, and works with portable EPR devices for on-site detection. This multi-functional marker system replaces the need for multiple different analytical methods and equipment, unifying detection capabilities across laboratory and field settings.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables quick and simple on-site detection of the origin and quality of hydrocarbon compositions, including those with water and urea, facilitating the identification of counterfeits and ensuring manufacturing process integrity without the need for complex equipment.

Implementation Method 1

the marking being monitored by Electronic Paramagnetic Resonance (EPR) (by detection of the radical compound)

Methodology Applied
Scientific EffectElectronic Paramagnetic Resonance (EPR): Electron Paramagnetic Resonance

Data Source

PatentEP4077602B1Marking composition
Publication Date: 2024.05.15 TOTALENERGIES ONETECH
  • EP4077602B1 patent drawingFigure 1
  • EP4077602B1 patent drawingFigure 2

AI summary

The present application relates to the use of a radical compound in a composition comprising at least one hydrocarbon or in an additive composition intended to be added to a composition comprising at least one hydrocarbon, to mark said hydrocarbon mixture.