Radical-Generating Catalyst for Mild-Condition Oxidation
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Existing radical generation methods require high energy input, leading to cost and reaction control issues, and existing bactericides using chlorine dioxide and hypochlorous acid face safety and stability concerns due to their explosive and unstable nature.
Innovation Solution
A radical generating catalyst comprising ammonium and/or its salts or organic compounds with Lewis and/or Brønsted acidic properties is used to produce radicals under mild conditions, combined with a radical source to generate oxidation reaction products.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Productivity
If high energy input methods are used to generate radicals, then radical generation efficiency is improved, but operational cost and reaction control difficulty increase
Solution Approach 1:
The patent replaces mechanical/thermal energy input systems with a chemical catalyst system. Instead of using heating equipment or high-energy mechanical methods to generate radicals, the invention employs a catalyst that facilitates radical generation through chemical reactions under mild conditions, thereby eliminating the need for complex energy input equipment and reducing operational costs.
Solution Approach 2:
The patent changes the reaction parameters from high-energy conditions (high temperature, high pressure) to mild conditions (room temperature, atmospheric pressure) by introducing a catalyst. This parameter change enables radical generation to proceed efficiently without requiring high energy input, thus reducing both operational cost and reaction control difficulty.
2Reliability
If chlorine dioxide is used as a bactericide, then sterilizing effect is improved, but safety and storage stability deteriorate due to explosive nature
Solution Approach 1:
The patent introduces a catalyst as an intermediary substance that enables the generation of active radicals from stable precursor compounds. The catalyst mediates the decomposition of stable compounds (like peroxides or hypohalites) to produce the desired radical species in situ, thereby avoiding the need to store and handle unstable and explosive chlorine dioxide gas directly.
Solution Approach 2:
The patent employs stable, non-explosive precursor compounds that can be stored safely and generate the required radical species temporarily when needed. These precursors act as safe substitutes for the unstable chlorine dioxide, providing the necessary sterilizing effect only when activated by the catalyst, after which they decompose into harmless products.
3Reliability
If hypochlorous acid is used as a bactericide, then sterilizing effect is achieved, but stability deteriorates due to immediate decomposition
Solution Approach 1:
The patent prepares stable precursor compounds in advance that contain the necessary chemical groups to generate hypochlorous acid or related radical species. These precursors are formulated with catalysts in a stable composition that prevents premature reaction, allowing the product to be stored for extended periods before use. When applied, the catalyst activates the precursors to generate the sterilizing agents in situ.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The catalyst enables safe and efficient radical generation and oxidation reactions at reduced costs, providing stable and high sterilizing effects for agricultural and livestock applications.
Implementation Method 1
a radical generating catalyst including: ammonium and/or a salt thereof
Implementation Method 2
sodium chlorite (NaClO 2 ) is a non-toxic inexpensive oxidizing reagent and has been used as a precursor of a chlorine dioxide radical (ClO 2 ·
Implementation Method 3
a method for producing an oxidation reaction product by oxidizing a substance to be oxidized
Data Source
Figure 1~2B
Figure 3A~4(c)
Figure 5(a)~5(c)
AI summary
An object of a first aspect of the present invention is to provide a radical generating catalyst that can generate (produce) radicals under mild conditions. In order to achieve the above object, a first radical generating catalyst according to the first aspect of the present invention is characterized in that it includes ammonium and/or a salt thereof. A second radical generating catalyst according to the first aspect of the present invention is characterized in that it includes an organic compound having Lewis acidic properties and/or Brønsted acidic properties.