Radioactive Dust Suppression Composition

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Solution Overview

Problem

Existing methods fail to form a continuous coating on surfaces covered with ash and smoldering embers during fire extinguishing, leading to ineffective containment of radioactive dust and contamination after a fire complicated by a radiation factor.

Innovation Solution

A composition comprising an aqueous solution of polyvinyl alcohol, a plasticizer, and a surfactant mixture, specifically glycerine and a blend of anionic, non-ionic, and amphoteric surfactants, which forms a stable foam that uniformly coats and absorbs ash particles, creating a continuous protective layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a foam containing polyvinyl alcohol is applied to surfaces covered by ash and smoldering embers, then a containment coating should form, but the foam does not form a continuous coating under these conditions

Engineering Contradiction:
Improvecontainment coating continuityVSAvoidapplicability to ash-covered surfaces
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent modifies the chemical composition parameters of the foam by incorporating specific surfactants (ionic and non-ionic) and plasticizers in controlled amounts. These parameter changes enable the foam to maintain stability and form continuous coatings on ash-covered surfaces where conventional foams fail, directly resolving the contradiction between coating continuity and adaptability to harsh surfaces.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite foam system combining polyvinyl alcohol with multiple surfactants and plasticizers. This composite formulation provides both the adhesion needed for continuous coating formation and the flexibility required to adapt to irregular ash-covered surfaces, simultaneously achieving reliability and versatility.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If a fire-extinguishing agent is applied to extinguish fire, then the fire is extinguished, but no polymer containment coating is formed on the surface

Engineering Contradiction:
Improvefire extinctionVSAvoidcontainment coating formation
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent merges two separate functions into a single composition: fire extinction (via foam formation and cooling) and containment coating formation (via polymer deposition). The foam-containing composition performs both functions simultaneously, eliminating the need for separate fire extinction and containment operations.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates a universal composition that serves multiple purposes: extinguishing fire, forming a containment coating, and preventing radioactive dust spread. This multi-functional agent replaces the need for sequential application of different substances, achieving both fire extinction and reliable containment coating formation.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Ease of manufacture

If a stabilization foam is used for decontamination, then cleaning is achieved, but it cannot suppress and contain radioactive products of combustion after fire extinguishing

Engineering Contradiction:
Improvefoam stabilityVSAvoidsuitability for radioactive contamination containment
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The patent tailors the foam composition with specific components (polyvinyl alcohol, surfactants, plasticizers) in precise proportions to achieve the local quality needed for radioactive contamination containment. The formulation provides enhanced adhesion and film-forming properties specifically suited for hot, ash-covered surfaces following fire extinction, making the foam adaptable to this specific application while maintaining stability.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition ensures a continuous coating on embers and ash, effectively preventing the spread of radioactive contaminants for over 180 days, maintaining stable foam properties and uniform wetting, even on hot surfaces.

Implementation Method 1

a surfactant mixture, specifically glycerine and a blend of anionic, non-ionic, and amphoteric surfactants, which forms a stable foam that uniformly coats and absorbs ash particles

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

an aqueous solution of polyvinyl alcohol... forms a continuous coating on embers and ash, effectively preventing the spread of radioactive contaminants

Methodology Applied
Scientific EffectFilm formation: Coatings

Implementation Method 3

particles from the upper layer of ash are absorbed into the bubble walls and start to migrate vigorously under the effect of alternating forces, drawing in more and more ash particles

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentEP3594967B1Composition for dust suppression and containment of radioactive products of combustion
Publication Date: 2024.05.22 GOSUDARSTVENNAJA KORPORATSIJA PO ATOMNOJ EHNERGII ROSATOM

AI summary

The invention relates to means for protecting the environment from the consequences of fires complicated by a radiation factor. A composition for dust suppression and containment of radioactive products of combustion after a fire with a radiation factor has been extinguished comprises, as a surfactant, a mixture of an anionic, a non-ionic and an amphoteric surfactant, and has the following ratio of components: 3.0-7.0% by weight of an aqueous solution of polyvinyl alcohol (in terms of a mass fraction of dry product); 0.1-0.3% by weight of plasticizer; 11.0-29.0% by weight of surfactant; with water making up the remainder. The invention makes it possible to carry out dust suppression and containment of radioactive products of combustion which are formed on surfaces, including at elevated temperatures, after a fire has been extinguished.