Radioactive Liquid Waste Treatment Apparatus with Electrostatic Colloid Removal

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Solution Overview

Problem

Current methods for treating radioactive liquid waste from nuclear facilities are inefficient in removing particulate and colloidal substances, leading to increased generation of radioactive waste and difficulty in adjusting pH to neutral levels, which affects the removal efficiency of radioactive nuclides.

Innovation Solution

A method involving a filtration device to remove particulate substances, followed by an electrostatic filter to remove colloidal substances, and multiple adsorption devices with specific adsorbents like oxine impregnated activated carbon to adjust pH and enhance the removal efficiency of radioactive nuclides, using oxidizing, reducing, or pH adjusting agents as needed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If only filtration device is used to remove particulate substances, then particulate removal is achieved, but colloidal substance removal is insufficient leading to increased radioactive waste generation

Engineering Contradiction:
Improveamount of radioactive waste generatedVSAvoidremoval efficiency of colloidal substances
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The treatment process is segmented into multiple stages: first removing particulate substances with a filtration device, then removing colloidal substances with an electrostatic filter, and finally removing radioactive nuclides with adsorption devices. This segmentation allows each device to specialize in removing specific types of contaminants, thereby reducing overall radioactive waste while maintaining high removal efficiency.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The electrostatic filter acts as an intermediary device between the filtration device and adsorption devices. It specifically targets colloidal substances that the filtration device cannot remove, using electrostatic attraction to capture charged colloidal particles. This intermediary step prevents colloidal substances from reaching the adsorption devices, reducing waste generation while maintaining effective contaminant removal.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If pH adjustment is performed using chemical agents, then pH neutralization is achieved, but the treatment process becomes more complex and requires additional chemical handling

Engineering Contradiction:
Improvesimplicity of treatment processVSAvoidnumber of treatment steps and equipment
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The adsorption devices perform dual functions: removing radioactive nuclides and simultaneously adjusting pH to neutral levels. The adsorbents used in these devices naturally buffer the pH of the liquid waste as they remove radioactive contaminants, eliminating the need for separate pH adjustment steps and chemical agents. This self-service approach simplifies the overall treatment process while maintaining operational ease.

Inventive Principle:
Principle #25Self-service

3Reliability

If multiple treatment devices are added to improve removal efficiency, then radioactive nuclide removal is enhanced, but the device complexity and process difficulty increase

Engineering Contradiction:
Improveremoval efficiency of radioactive nuclidesVSAvoidnumber of devices and process steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

Each treatment device in the series is designed with multi-functionality to justify its inclusion. The electrostatic filter removes both colloidal substances and contributes to overall contaminant reduction. The adsorption devices simultaneously remove radioactive nuclides and adjust pH levels. This multi-functionality reduces the need for additional specialized devices, thereby limiting overall system complexity while maintaining high removal efficiency.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the amount of radioactive waste generated, achieves efficient removal of radioactive nuclides, and adjusts the pH of treated water to a neutral range without adding chemical agents, thereby simplifying the treatment process and improving removal efficiency.

Implementation Method 1

a filtration device to remove particulate substances

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Implementation Method 2

an electrostatic filter to remove colloidal substances

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 3

radioactive nuclides are removed from radioactive liquid waste using an ion exchange resin or the like through adsorption

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS9799418B2Method of treating radioactive liquid waste and radioactive liquid waste treatment apparatus
Publication Date: 2017.10.24 HITACHI GE NUCLEAR ENERGY LTD
  • US9799418B2 patent drawing
  • US9799418B2 patent drawing
  • US9799418B2 patent drawing

AI summary

Provided is a method of treating radioactive liquid waste which reduces the amount of radioactive waste to be generated and is capable of removing a radioactive nuclide from radioactive liquid waste to the extent that the concentration thereof is less than or equal to the measurement lower limit using a simple apparatus configuration. A filtration device is connected to a colloid removal device by a connection pipe. An adsorption tower positioned at the highest stream of an adsorption device is connected to the colloid removal device by a connection pipe. The colloid removal device includes an electrostatic filter. Respective adsorption towers in the adsorption device are sequentially connected by a pipe. A discharge pipe is connected to the adsorption tower positioned at the lowest stream of the adsorption device. Radioactive liquid waste, containing particles having a particle diameter of 1 μm or greater, negatively charged colloids, and a radioactive nuclide, is supplied to the filtration device. The particles having a particle diameter of 1 μm or greater are removed by the filtration device and the negatively charged colloids are removed by the electrostatic filter that is positively charged. The radioactive nuclide is removed by the adsorption tower.