Combined Raman and LIBS Detection System for Threat Agents

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Solution Overview

Problem

Current threat detection methods are inefficient and labor-intensive, relying on separate instrumentation for detection and identification of threat agents, with limitations in sensitivity and specificity, particularly in the use of Raman and LIBS spectroscopy for airborne and biological threats.

Innovation Solution

A combined Raman and LIBS system optimized for threat detection, utilizing structured illumination and chemometric spectral processing to enhance sensitivity and specificity, allowing for simultaneous Raman and LIBS data analysis without reagents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If separate instrumentation is used for detection and identification of threat agents, then detection coverage is broad, but detection efficiency and productivity are low

Engineering Contradiction:
Improvedetection efficiencyVSAvoidseparate instrumentation
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent combines Raman spectroscopy and LIBS techniques into a single integrated system that performs both detection and identification functions simultaneously. The system uses a shared optical path, detector, and processing unit to acquire both molecular fingerprint data (Raman) and elemental composition data (LIBS) from the same sample, thereby improving productivity while managing device complexity through unified architecture

Inventive Principle:
Principle #5Merging (Combining)

2Measurement precision

If Raman spectroscopy is used for threat agent identification, then molecular specificity is high, but sensitivity to certain threats is insufficient

Engineering Contradiction:
Improvemolecular specificityVSAvoiddetection sensitivity
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent creates a composite analytical approach by fusing Raman spectroscopy data with LIBS data. The Raman component provides molecular specificity through vibrational fingerprinting, while the LIBS component contributes elemental sensitivity through atomic emission spectroscopy. The chemometric fusion of these two complementary data types produces a combined detection system with both high specificity and high sensitivity, overcoming the limitations of either technique alone

Inventive Principle:
Principle #40Composite materials

3Reliability

If LIBS is used for threat agent detection, then elemental sensitivity is high, but molecular specificity is reduced

Engineering Contradiction:
Improvedetection sensitivityVSAvoidmolecular specificity
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent creates a composite analytical approach by fusing Raman spectroscopy data with LIBS data. The Raman component provides molecular specificity through vibrational fingerprinting, while the LIBS component contributes elemental sensitivity through atomic emission spectroscopy. The chemometric fusion of these two complementary data types produces a combined detection system with both high specificity and high sensitivity, overcoming the limitations of either technique alone

Inventive Principle:
Principle #40Composite materials

4Ease of operation

If conventional spectroscopic methods are used for identification, then reagent-free detection is achieved, but false positives occur due to background interference

Engineering Contradiction:
Improvereagent-free detectionVSAvoidfalse positive rate
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent introduces chemometric spectral processing algorithms as an intermediary between the raw spectral data and the final identification result. These algorithms process and analyze the fused Raman and LIBS spectral data, applying pattern recognition and statistical methods to distinguish true threat signals from background interference. This intermediary processing layer maintains the simplicity of reagent-free detection while significantly reducing false positives through intelligent data analysis

Inventive Principle:
Principle #24Intermediary (Mediator)

Data Source

PatentUS7999928B2Method and system for combined Raman and LIBS detection
Publication Date: 2011.08.16 CHEMIMAGE CORP
  • US7999928B2 patent drawing
  • US7999928B2 patent drawing
  • US7999928B2 patent drawing

AI summary

In one embodiment, the disclosure relates to a method for interrogating a sample by: illuminating a first region of the sample with a first illumination pattern to obtain a plurality of first sample photons; illuminating a second region of the sample with a second illumination pattern to obtain a plurality of second sample photons; processing the plurality of first sample photons to obtain a characteristic atomic emission of the first region and processing the plurality of second sample photons to obtain a Raman spectrum; and identifying the sample through at least one of the characteristic atomic emission of the first region or the Raman spectrum of the second region of the sample.