Multi-Wavelength Raman Spectroscopy Optical Path Design

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional Raman spectroscopy devices require complex adjustments and component replacements when changing excitation wavelengths, making them inefficient for analyzing unknown substances, especially in portable devices, due to fixed optical elements and limited flexibility in selecting optimal wavelengths for Raman signal generation.

Innovation Solution

A device with multiple excitation light sources emitting wavelengths equidistant in wavenumbers, using deflection devices with specific transmission properties to direct excitation and Raman radiation to a common path without moving parts, allowing simultaneous or sequential detection of Raman spectra across a wide spectral range without mechanical adjustments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional Raman spectroscopy devices use fixed optical elements and single excitation wavelength, then device structure is simple, but adaptability for analyzing unknown substances is poor

Engineering Contradiction:
Improveadaptability for analyzing unknown substancesVSAvoiddevice structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The device segments the excitation light source into multiple independent laser sources with different wavelengths (e.g., 532nm, 785nm, 1064nm). Each wavelength can be independently selected and directed to the sample through optical switching mechanisms, allowing the system to adapt to different sample types without redesigning the entire optical path.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The optical system is designed with universal components that can handle multiple wavelengths simultaneously. The same objective lens, filters, and detectors can process excitation and Raman signals across different spectral ranges, making the device versatile for various applications while maintaining a compact structure.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Ease of operation

If conventional devices require mechanical adjustments when changing wavelengths, then optical optimization is achievable, but ease of operation deteriorates

Engineering Contradiction:
Improveease of operationVSAvoidoptical optimization
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The device replaces mechanical adjustment mechanisms with solid-state optical switching. Digital controls and software interfaces allow users to select different excitation wavelengths without any physical movement or alignment adjustments, significantly improving ease of operation while maintaining optical precision through pre-aligned optical paths.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The optical system incorporates dynamically switchable components such as acousto-optic modulators or electro-optic switches that can rapidly change the excitation wavelength on demand. This dynamic capability allows the system to adapt to different measurement requirements in real-time without mechanical intervention.

Inventive Principle:
Principle #15Dynamics

3Adaptability or versatility

If conventional devices use fixed optical paths, then device complexity is reduced, but adaptability for different spectral ranges deteriorates

Engineering Contradiction:
Improvespectral range coverageVSAvoidoptical path configuration
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The device merges multiple excitation paths and detection paths into a single integrated optical system. Multiple laser sources are combined using beam combining optics, and the Raman signals from different wavelengths are collected through a common detection path, allowing broad spectral coverage without proportionally increasing device complexity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The optical system employs a nested architecture where shorter wavelength optical paths are integrated within the framework of longer wavelength paths. For example, the 532nm optical components are nested within the 1064nm system, sharing common elements like the objective lens and detector, thereby achieving multi-spectral capability with compact design.

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables efficient generation and detection of Raman spectra over a large spectral range without mechanical adjustments, allowing for the selection of optimal wavelengths for unknown samples, enhancing signal intensity and noise ratio, and providing a robust, compact, and adaptable measurement system.

Implementation Method 1

excitation light sources for the emission of individual light beams with different wavelengths

Methodology Applied
Scientific EffectLight emission from laser sources: Laser

Implementation Method 2

deflection devices which, for a respective first wavelength of the excitation radiation on the light path, are designed to deflect the respective light path onto a common light path

Methodology Applied
Scientific EffectOptical deflection and filtering: Filter (optical)

Implementation Method 3

the common light path having optics which are arranged outside the device in order to focus the excitation radiation onto a focal point

Methodology Applied
Scientific EffectLight focusing: Focusing

Implementation Method 4

a small part of the light is inelastically scattered in addition to absorption and emission. The signals characteristic of each sample are called Raman signals. They are spectrally shifted towards the excitation wavelength

Methodology Applied
Scientific EffectRaman scattering: Scattering

Implementation Method 5

A bandpass filter specially adapted to the excitation wavelength suppresses the stray light emitted by the excitation source, such as plasma lines in gas lasers or amplified spontaneous emission (ASE) in diode lasers

Methodology Applied
Scientific EffectOptical filtering: Filter (optical)

Implementation Method 6

Long-pass filters or notch filters can be selected for the detection of Stokes lines

Methodology Applied
Scientific EffectSpectral separation: Filter (optical)

Data Source

PatentEP2895844B1Apparatus with an arrangement of optical elements
Publication Date: 2018.11.07 FORSCHUNGSVERBUND BERLIN EV
  • EP2895844B1 patent drawingFigure 1
  • EP2895844B1 patent drawingFigure 2
  • EP2895844B1 patent drawingFigure 3

AI summary

The invention relates to a device (122) having an arrangement of optical elements, comprising excitation light sources (101, 115) for producing individual light beams (102, 116) having different wavelengths for exciting a sample in such a way that light scattered back by the sample as a result of the excitation is made available to a Raman spectroscopic analysis. The device (122) comprises deflecting devices (103, 117) associated with the individual light beams (102, 116) for deflecting the individual light beams (102, 116) onto a common light path, wherein the common light path comprises a common optical system (109) for focusing the light beams (102, 116).