Raman Probe Optical Filters for Signal Purity

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Solution Overview

Problem

Current Raman spectroscopy systems face challenges in delivering laser light and collecting Raman signals due to space limitations in portable systems and signal distortions from Amplified Spontaneous Emission (ASE), as well as fluorescence and Raleigh and Raman scatterings introduced by optical fibers.

Innovation Solution

An improved Raman spectroscopy system with a Raman probe that separates the pump source from the Raman signal, filters out ASE, fluorescence, and Raleigh and Raman scatterings, and allows for three modes of use: maintaining distance with a conical standoff, manual distance control, and direct insertion of a specimen vial, using optical elements and filters to enhance signal quality and safety.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If optical fibers are used to deliver laser light and collect Raman signals remotely, then space limitations are reduced and remote measurement is enabled, but fluorescence and Raleigh and Raman scatterings are introduced into the system

Engineering Contradiction:
Improvespace availabilityVSAvoidfluorescence and scattering
Core Design Contradiction:
Volume of moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent extracts and removes the harmful fluorescent and scattered signals generated by optical fibers through the use of spectral filters. The filter selectively transmits the Raman signal while blocking the fluorescent background and Rayleigh scattering, thereby eliminating the harmful effects introduced by fiber optic delivery

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces an optical filter as an intermediary element between the optical fiber and the detector. This intermediary component mediates the interaction by allowing the desired Raman signal to pass through while blocking the harmful fluorescent and scattered light, thus resolving the contradiction between using fibers for remote delivery and avoiding fiber-generated interference

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If ASE background from laser sources is present in the system, then laser light delivery is simplified, but signal distortion and reduced measurement precision occur

Engineering Contradiction:
Improvesystem simplicityVSAvoidsignal quality
Core Design Contradiction:
Ease of manufactureVSMeasurement precision

Solution Approach 1:

The patent converts the harmful ASE background into a beneficial filtering opportunity. By using a spectral filter that blocks the ASE wavelength range while transmitting the Raman signal, the system transforms the problematic ASE emission into a defined spectral region that can be easily filtered out, thereby improving signal quality without complicating the laser delivery system

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent introduces a spectral filter as an intermediary component that selectively transmits the Raman signal while blocking the ASE background from the laser source. This intermediary element resolves the contradiction by maintaining simple laser delivery while eliminating signal distortion through wavelength-selective filtering

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If multiple filtering operations are performed to remove unwanted signals, then signal quality is improved, but device complexity increases

Engineering Contradiction:
Improvesignal qualityVSAvoidnumber of optical elements
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent combines multiple filtering functions into a single integrated optical filter component. This single filter simultaneously blocks ASE background, Rayleigh scattering, and fluorescent signals while transmitting the Raman signal, thereby achieving high signal quality without the complexity of multiple separate filtering stages

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent employs a universal optical filter that performs multiple filtering functions in one component. The filter is designed to block multiple types of unwanted signals (ASE, Rayleigh scattering, fluorescence) across different wavelength ranges while transmitting the Raman signal, thus achieving comprehensive signal purification with a single multi-functional element

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively filters out unwanted signals and allows for precise identification and characterization of specimens, improving signal quality and safety in portable and remote applications.

Implementation Method 1

a first filter for receiving light from the first optical fiber and adapted to pass the laser excitation light and to block spurious signals associated with the light

Methodology Applied
Scientific EffectOptical filtering: Filter (optical)

Implementation Method 2

the second filter is further configured so that when the second filter receives the Raman signal from the focusing apparatus, the second filter filters out unwanted laser excitation light before directing the Raman signal to a second optical fiber

Methodology Applied
Scientific EffectOptical filtering: Filter (optical)

Implementation Method 3

focusing apparatus for receiving the light from the second filter, focusing the light on the specimen so as to generate the Raman signal

Methodology Applied
Scientific EffectOptical focusing: Focusing

Implementation Method 4

a first optical fiber for receiving laser excitation light from a light source and transmitting the same

Methodology Applied
Scientific EffectOptical fiber transmission: Optical Fibre

Data Source

PatentUS7636157B2Method and apparatus for conducting Raman spectroscopy
Publication Date: 2009.12.22 AHURA CORP
  • US7636157B2 patent drawing
  • US7636157B2 patent drawing
  • US7636157B2 patent drawing

AI summary

Disclosed herein are Raman probes that include: (a) a first optical fiber for receiving laser excitation light from a light source and transmitting the same; (b) a first filter for receiving light from the first optical fiber and adapted to pass the laser excitation light and to block spurious signals associated with the light; (c) a second filter for receiving light from the first filter and adapted to direct the light toward a specimen; and (d) focusing apparatus for receiving the light from the second filter, focusing the light on the specimen so as to generate the Raman signal, and returning the Raman signal to the second filter. The second filter is further configured so that when the second filter receives the Raman signal from the focusing apparatus, the second filter filters out unwanted laser excitation light before directing the Raman signal to a second optical fiber.