Random Multi-Component Polymers for Water Remediation

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Solution Overview

Problem

Current flocculation methods using poly(NIPAAm) are insufficient for removing a majority of aqueous pollutants and require multiple treatments, necessitating the development of improved random multi-component polymers with enhanced flocculation properties above the low critical solution temperature (LCST) for effective water remediation.

Innovation Solution

Random multi-component polymers comprising specific monomer components, including Formula (I), Formula (II), and Formula (III), which are water miscible below a certain temperature and convert to hydrophobic forms above the LCST, facilitating easy separation and enhanced flocculation of aqueous pollutants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If poly(NIPAAm) is used for flocculation above LCST, then temperature-responsive flocculation is achieved, but the removal efficiency of aqueous pollutants remains insufficient

Engineering Contradiction:
Improveflocculation efficiencyVSAvoidpollutant removal efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies composite materials by combining poly(NIPAAm) with other polymer components to create multi-component flocculants. This composite approach integrates the temperature-responsive properties of poly(NIPAAm) with additional functional groups that enhance flocculation efficiency and pollutant removal capability, resolving the contradiction between achieving temperature-responsive flocculation and maintaining high removal efficiency

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes parameter changes by modifying the chemical composition and structure of the polymer flocculants. By changing parameters such as monomer composition, molecular weight, and functional group content, the flocculants achieve both temperature-responsive behavior and enhanced pollutant removal efficiency, simultaneously improving reliability and productivity

Inventive Principle:
Principle #35Parameter changes

2Productivity

If multiple treatments are applied to remove pollutants, then removal efficiency improves, but treatment time and process complexity increase

Engineering Contradiction:
Improvepollutant removal efficiencyVSAvoidtreatment time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent applies universality by designing flocculants that can remove multiple types of pollutants (both soluble and insoluble) through a single treatment process. The multi-component polymer structure provides diverse functional groups that can interact with various pollutant types, eliminating the need for multiple sequential treatments and reducing overall treatment time

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Ease of operation

If flocculated polymers are easily separated from water, then separation efficiency improves, but flocculation strength may be reduced

Engineering Contradiction:
Improveseparation easeVSAvoidflocculation strength
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies phase transitions by utilizing the LCST (lower critical solution temperature) behavior of poly(NIPAAm). Below the LCST, the polymer is hydrophilic and soluble in water; above the LCST, it undergoes a phase transition to become hydrophobic and precipitates as easy-to-separate flocs. This phase transition mechanism enables both strong flocculation and easy separation without compromise

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These polymers demonstrate high efficiency in sequestering soluble and insoluble particles from aqueous streams, achieving significant removal of pollutants with a single treatment and allowing for easy separation and recovery.

Implementation Method 1

the random multi-component polymers or salts thereof are water miscible and associates with a soluble species or insoluble particle below a specific temperature and then at or above a specific temperature, converts to a flocculated random multi-component polymers or salts thereof is hydrophobic

Methodology Applied
Scientific EffectPhase transition (LCST): Phase Change

Implementation Method 2

This flocculation occurs through hydrophobic association of polymer chains and removes various aqueous pollutants (particles)

Methodology Applied
Scientific EffectHydrophobic association: Hydrophobe

Implementation Method 3

Water remediation utilizing sorption has found strong interest due to its inexpensiveness, universal nature, and ease of operation

Methodology Applied
Scientific EffectSorption: Sorption

Data Source

PatentUS20230390672A1Improved flocculants
Publication Date: 2023.12.07 UNIVERSITY OF KENTUCKY RESEARCH FOUNDATION
  • US20230390672A1 patent drawing
  • US20230390672A1 patent drawing
  • US20230390672A1 patent drawing

AI summary

The present invention provides random multi-component polymers, methods to prepare the random multi-component polymers, methods for removing soluble species or insoluble particles from an aqueous solution, and methods for removing soluble species or insoluble particles from an aqueous solution in the human body