Rapeseed Oil Surfactant Scouring Agent for Sustainable Cleaning

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Solution Overview

Problem

The extraction of surfactants from tropical palm kernel and coconut oil for liquid scouring agents leads to overexploitation of tropical rainforests, causing environmental damage and sustainability concerns, as these agents end up in wastewater and are not easily broken down.

Innovation Solution

A liquid scouring agent using PEG-4 rapeseedamide as a surface-active substance derived from technical rapeseed oil, combined with marble powder as an abrasive, which provides stable and effective cleaning properties without competing with food sources and minimizing environmental impact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If surfactants are extracted from tropical palm kernel or coconut oil, then effective cleaning properties are achieved, but environmental damage and sustainability concerns arise due to overexploitation of tropical rainforests

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidenvironmental damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the source parameter of the surfactant from tropical oils to rapeseed oil-based PEG-4 rapeseedamide, maintaining the necessary HLB value and surface-active properties while eliminating the environmental harm associated with tropical rainforest exploitation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses rapeseed oil, a readily available and sustainable European vegetable oil, as a renewable resource that can be continuously produced without depleting natural habitats, replacing the finite and environmentally damaging tropical oil sources

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If C18 compounds with multiple double bonds are used as surfactants, then effective surface activity is achieved, but oxidative and microbiological spoilage increases

Engineering Contradiction:
Improvesurface activityVSAvoidoxidative stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent modifies the chemical structure by ethoxylating the rapeseed oil amines to create PEG-4 rapeseedamide, which maintains the necessary surface activity while the resulting molecular structure shows improved stability, particularly when used in opaque packaging that protects from sunlight-induced oxidation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces phenoxyethanol as a preservative synergist that acts as an intermediary protective agent, preventing microbiological attack on the C18 compounds with multiple double bonds, thereby maintaining both surface activity and stability

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If transparent bottles are used for packaging the scouring agent, then product visibility is improved, but oxidative degradation increases due to sunlight exposure

Engineering Contradiction:
Improveproduct visibilityVSAvoidoxidative stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent uses opaque plastic packaging that blocks sunlight, preventing photo-induced oxidative degradation of the PEG-4 rapeseedamide and marble powder mixture, thereby maintaining product stability without requiring additional UV filters or stabilizers

Inventive Principle:
Principle #32Color changes

4Reliability

If tropical vegetable oil surfactants are used in liquid scouring agents, then effective cleaning is achieved, but biodegradability and environmental sustainability are compromised

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidbiodegradability
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent changes the fatty acid source from tropical oils to rapeseed oil, creating PEG-4 rapeseedamide which maintains effective HLB values for cleaning while being derived from a sustainable, European-based vegetable oil that is readily biodegradable and does not contribute to rainforest destruction

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of PEG-4 rapeseedamide and marble powder in the scouring agent achieves high storage stability, improved rinsability, and reduced water consumption, with enhanced flow behavior and cleaning power, while being biodegradable and free from the need for additional stabilizers, thus addressing sustainability and performance issues.

Implementation Method 1

PEG-4 rapeseedamide (INCI name) is used as a surface-active substance in a liquid scouring agent

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

Marble powder is used as an abrasive in conjunction with PEG-4 rapeseedamide

Methodology Applied
Scientific EffectAbrasion: Abrasion

Implementation Method 3

A scouring agent containing 40% by weight of marble powder and only 2.0% by weight of PEG-4 rapeseedamide has a very high viscosity at very low shear rates or at rest. At shearing speeds, such as those that occur at the bottle neck when pouring out of a bottle, there is a relatively steep drop in viscosity

Methodology Applied
Scientific EffectShear thinning: Shear Thinning

Implementation Method 4

the main cause of oxidative degradation is induced by sunlight, which cannot affect the product due to opaque plastic packaging

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentEP2865740B1Liquid scouring composition
Publication Date: 2017.04.26 WERNER & MERTZ GMBH

AI summary

The invention relates to a liquid scouring agent containing as a surfactant one or more substances with monounsaturated and/or polyunsaturated C18 alkyl chains, wherein the surfactant is a non-ionic surfactant based on rapeseed oil, and an abrasive, in particular marble flour, is used in combination with the surfactant.