Rare Earth Additive for Microbial Biotransformation of Low-Rank Coal

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Solution Overview

Problem

Low-rank coal combustion leads to severe ecological and environmental pollution, with limited efficiency in direct combustion or gasification due to its low degree of coalification, high volatile matter content, and high moisture content, and there is a need to utilize rare earth elements to enhance microbial transformation for improved material utilization and reduced pollution.

Innovation Solution

A rare earth additive composed of rare earth chlorides, mixed rare earth chlorides, and rare earth nitrates, specifically lanthanum, cerium, ytterbium, and neodymium compounds, is used to improve microbial biotransformation efficiency, promoting the conversion of low-rank coal and biomass into clean energy sources like biomethane, biohydrogen, and high-value chemicals, by enhancing microbial metabolic pathways and cell membrane permeability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If low-rank coal is used for direct combustion or gasification, then energy production is achieved, but material utilization efficiency is limited and severe ecological and environmental pollution occurs

Engineering Contradiction:
Improvematerial utilization efficiencyVSAvoidecological and environmental pollution
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces rare earth elements (specifically rare earth salts or compounds) as intermediaries to mediate between low-rank coal and microbial communities. These rare earth substances act as catalysts or promoters that enhance microbial metabolic activity, thereby improving the efficiency of converting low-rank coal into useful products while reducing harmful emissions. The rare earth elements facilitate biochemical reactions that would otherwise be inefficient or polluting.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical and biological parameters of the coal transformation process by adding rare earth elements. This shifts the transformation pathway from direct combustion (high temperature, oxygen-intensive) to enhanced microbial biotransformation (lower temperature, enzyme-catalyzed). The rare earth elements modify reaction kinetics, microbial community structure, and product distribution, thereby improving material utilization and reducing pollution.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If rare earth additive is used to enhance microbial biotransformation, then production efficiency of clean energy and high-value chemicals is significantly improved, but cost of additive preparation and application increases

Engineering Contradiction:
Improveproduction efficiency of clean energy and high-value chemicalsVSAvoidcost of additive preparation and application
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent optimizes the concentration and composition parameters of rare earth additives to achieve maximum catalytic effect at minimum cost. By determining optimal dosage ranges and selecting cost-effective rare earth compounds (such as using more abundant rare earth elements), the patent balances performance enhancement with economic feasibility.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite rare earth formulations, combining multiple rare earth elements or mixing rare earth compounds with other materials to enhance catalytic activity while reducing the amount of expensive rare earth substances needed. This composite approach allows for synergistic effects that improve production efficiency while controlling costs.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The rare earth additive significantly enhances the efficiency of microbial biotransformation, increasing the production of clean energy and high-value chemicals, reducing carbon consumption, and facilitating the graded transformation and tiered utilization of low-rank coal resources, while being cost-effective and suitable for large-scale industrial production.

Implementation Method 1

enhancing microbial metabolic pathways and cell membrane permeability

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 2

enhancing microbial metabolic pathways

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS20240409428A1Rare earth auxiliary agent and preparation method therefor
Publication Date: 2024.12.12 INNER MONGOLIA UNIV OF SCI & TECH
  • US20240409428A1 patent drawing
  • US20240409428A1 patent drawing

AI summary

This present disclosure provides a rare earth additive and a method for preparing the rare earth additive to be used in production of clean energy or high-value chemicals, by which utilization of low-rank coal and biomass resources is achieved. The rare earth additive of the present disclosure is composed of rare earth chlorides, mixed rare earth chlorides, and rare earth nitrates, and can be used as additive for biochemical reactions between microorganisms and substances to be transformed, so as to improve the microbial activity in biochemical reactions. The rare earth additive promotes the transformation of low-rank coal (peat, lignite, sub-bituminous coal, weathered coal, coal gangue) and biomass into clean energy sources such as biomethane, biohydrogen, or bioethanol and high-value chemicals such as fulvic acid, water-soluble humic acid, benzoic acid, benzaldehyde, benzyl alcohol. The carbon reduction transformation of high-carbon resources such as low-rank coal and biomass may be achieved.