Rare-Earth Regenerator Particles for Cryogenic Gas Permeability

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Solution Overview

Problem

Conventional regenerator materials for cryogenic refrigerators face challenges in achieving high-density filling and maximizing the contact surface area with the operating medium gas, such as helium, which affects the refrigerating performance and reliability, especially at extremely low temperatures.

Innovation Solution

Rare-earth regenerator material particles with specific size and shape characteristics, including an average particle size of 0.01 to 3 mm, a high proportion of particles with an aspect ratio of 2 or less, and a significant proportion of depressed portions on the surface, are developed to enhance packing density and contact surface area, utilizing manufacturing methods like the Rotary Disc Process and rotary nozzle process to produce these particles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If spherical particles are used for high-density filling, then packing density is improved, but contact surface area with He gas is reduced

Engineering Contradiction:
Improvepacking densityVSAvoidcontact surface area
Core Design Contradiction:
Quantity of substanceVSArea of stationary object

Solution Approach 1:

The patent applies asymmetry by introducing non-spherical shapes (cubes, irregular particles) with specific surface area enhancements. These asymmetric particles provide both high packing density and increased contact surface area with He gas, resolving the contradiction between spherical shape benefits and surface area requirements.

Inventive Principle:
Principle #4Asymmetry

Solution Approach 2:

The patent changes particle size parameters and shape parameters to optimize performance. By controlling particle size distribution and introducing shape variations, the patent achieves high-density filling while maintaining large contact surface area for heat exchange with He gas.

Inventive Principle:
Principle #35Parameter changes

2Area of stationary object

If smaller particles are used to increase contact surface area, then contact surface area is improved, but permeability of He gas decreases

Engineering Contradiction:
Improvecontact surface areaVSAvoidpermeability
Core Design Contradiction:
Area of stationary objectVSProductivity

Solution Approach 1:

The patent applies local quality by creating particles with surface features (protrusions, depressions, rough surfaces) that increase contact area locally without reducing overall particle size. This maintains He gas permeability while enhancing contact surface area for heat exchange.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments particles into specific size distributions, combining finer particles for surface area with coarser particles for permeability. This segmentation allows the regenerator material to simultaneously achieve high contact surface area and adequate gas flow permeability.

Inventive Principle:
Principle #1Segmentation

3Quantity of substance

If particles are filled under high pressure to increase density, then packing density is improved, but particle crushing occurs causing clogging

Engineering Contradiction:
Improvepacking densityVSAvoidsystem clogging
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent uses particles with rounded surfaces and smooth contours that resist crushing under filling pressure. The curved surfaces distribute stress more evenly, preventing particle fragmentation and subsequent clogging while achieving high packing density.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Solution Approach 2:

The patent employs composite particle structures with enhanced mechanical strength, combining materials or structures that maintain integrity under high filling pressure. This prevents particle crushing and ensures reliable long-term operation without clogging.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS10385248B2Rare-earth regenerator material particles, and group of rare-earth regenerator material particles, refrigerator and measuring apparatus using the same, and method for manufacturing the same
Publication Date: 2019.08.20 NITERRA MATERIALS CO LTD
  • US10385248B2 patent drawing
  • US10385248B2 patent drawing
  • US10385248B2 patent drawing

AI summary

Provided is a group of rare-earth regenerator material particles having an average particle size of 0.01 to 3 mm, wherein the proportion of particles having a ratio of a long diameter to a short diameter of 2 or less is 90% or more by number, and the proportion of particles having a depressed portion having a length of 1/10 to ½ of a circumferential length on a particle surface is 30% or more by number. By forming the depressed portion on the surface of the regenerator material particles, it is possible to increase permeability of an operating medium gas and a contact surface area with the operating medium gas.