Re-Entrant Porous Filter Structures for Fluorine-Free Liquid Repellency

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Solution Overview

Problem

Existing filtration technologies face challenges in preventing wetting and contamination by liquids without using environmentally unfriendly fluorinated chemicals, particularly in achieving hydrophobicity and oleophobicity.

Innovation Solution

A filter material with a layer of porous material and re-entrant structures disposed on its surface, such as hoodoo structures, which invert the meniscus of a liquid droplet to prevent wetting and maintain porosity, thereby enhancing hydrophobicity and oleophobicity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If fluorinated polymer coatings are applied to achieve hydrophobicity, then liquid repellency is improved, but environmental sustainability deteriorates

Engineering Contradiction:
Improveliquid repellencyVSAvoidenvironmental sustainability
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The invention extracts and removes the fluorinated polymer coating from the filtration system, achieving liquid repellency through the porous material's intrinsic properties and surface geometry alone. This eliminates the harmful fluorinated chemicals while maintaining the desired hydrophobicity and oleophobicity through the material's pore structure and surface energy characteristics.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention utilizes the porous structure of the filtration material itself to achieve liquid repellency. By optimizing the pore size, distribution, and surface energy of the porous material, the system creates hydrophobic and oleophobic properties without requiring additional fluorinated coatings, thus resolving the environmental sustainability issue while maintaining liquid repellency.

Inventive Principle:
Principle #31Porous materials

2Productivity

If conventional filtration materials are used, then filtration function is provided, but wetting and contamination by liquids occurs

Engineering Contradiction:
Improvefiltration functionVSAvoidwetting and contamination
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The invention applies local quality modifications to the filtration material by creating regions with different pore sizes, surface energies, or geometric configurations. This local variation in properties allows the material to maintain high filtration efficiency in certain zones while providing liquid repellency and preventing wetting in other zones, thus resolving the contradiction between filtration function and liquid resistance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The re-entrant structures effectively repel liquids by inverting the meniscus, reducing the risk of clogging and maintaining permeability, without the need for fluorinated coatings, thus improving filtration efficiency and environmental sustainability.

Implementation Method 1

The re-entrant structures effectively repel liquids by inverting the meniscus

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

increase the hydrophobicity and/or oleophobicity of the material

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Implementation Method 3

increase the hydrophobicity and/or oleophobicity of the material

Methodology Applied
Scientific EffectOleophobicity: Hydrophobe

Implementation Method 4

maintaining permeability

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 5

re-entrant geometries on a porous material surface

Methodology Applied
Scientific EffectCapillary pressure: Capillary Pressure

Data Source

PatentUS12383871B2Structures having re-entrant geometries on a porous material surface
Publication Date: 2025.08.12 DONALDSON CO INC
  • US12383871B2 patent drawing
  • US12383871B2 patent drawing
  • US12383871B2 patent drawing

AI summary

A filter material has a layer of porous material and a plurality of structures disposed on a surface of the layer, where each of the structures has a re-entrant geometry. The plurality of structures may be a plurality of ordered structures. A filter material may include a layer of porous material and a plurality of re-entrant structures disposed on a surface of the layer, each of the re-entrant structures including a stem and a cap, where the caps of adjacent structures are attached to each other to form a plurality of pores, where each pore is disposed between adjacent re-entrant structures.