Hierarchical Reactive Composite for Controlled Wellbore Disintegration

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Solution Overview

Problem

Existing disintegrating materials used in well completion processes have limitations such as limited strength and poor reliability, making them unsuitable for long-term storage and reliable disintegration upon activation.

Innovation Solution

A hierarchically-designed reactive composite system with a core and surface layers, where the core is designed to react at a high rate and the surface layers inhibit reaction until activated by specific conditions like temperature, pH, or chemicals, allowing for controlled disintegration in well environments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If reactive materials are used for disintegration in well completion, then disintegration function is achieved, but reliability and strength are poor

Engineering Contradiction:
Improvedisintegration reliabilityVSAvoidcomponent strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The system is divided into two distinct segments: a protective coating layer and a reactive core material. The coating layer maintains structural integrity and strength during storage and handling, while the reactive core provides the disintegration function. This segmentation allows each component to optimize its specific function without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The protective coating is applied in advance to the reactive core material before use. This preliminary protective action prevents premature reaction during storage, handling, and installation, ensuring the component remains strong and intact until the intended activation moment in the well environment.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If reactive materials are used for disintegration, then disintegration function is achieved, but storage stability deteriorates

Engineering Contradiction:
Improvedisintegration reliabilityVSAvoidstorage stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The protective coating acts as an intermediary barrier between the reactive core material and the external environment (water, oxygen, other chemicals). This intermediary layer prevents direct contact that would trigger unwanted reactions during storage, while allowing controlled activation when needed in the well environment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The reactive core material is extracted and isolated from direct environmental exposure by enclosing it within the protective coating. This extraction of the reactive material from harmful environmental interactions during storage maintains stability while preserving the disintegration function for later activation.

Inventive Principle:
Principle #2Taking out (Extraction)

3Productivity

If unprotected reactive materials are used, then disintegration occurs rapidly, but control over disintegration timing is lost

Engineering Contradiction:
Improvedisintegration speedVSAvoidtiming control
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The protective coating is applied in advance to prevent premature reaction, ensuring the component remains stable during storage and installation. The coating is designed to remain intact until the intended activation moment, providing reliable timing control.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The coating material is selected with specific properties (thickness, chemical composition, permeability) that control the timing and conditions of activation. By adjusting these parameters, the system achieves both rapid disintegration when activated and precise control over when activation occurs.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the formation of components that can be stored for extended periods and reliably disintegrate upon activation, improving the efficiency and reliability of well completion processes by ensuring controlled and repeatable disintegration.

Implementation Method 1

The core can be designed to dissolve, corrode, react, fracture, etc. when exposed to the water and/or to saltwater/electrolytes... thereby causing the component to dissolve or disintegrate in the well. The core can be designed to generate heat when exposed to various environments

Methodology Applied
Scientific EffectExothermic reaction: Exothermic Reaction

Implementation Method 2

reactive materials, which dissolve or corrode when exposed to acid, salt, or other wellbore conditions

Methodology Applied
Scientific EffectCorrosion: Crevice Corrosion

Implementation Method 3

dissolve, corrode, react, fracture, etc. when exposed to the water and/or to saltwater/electrolytes

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 4

one or more surfaces or protective layers that inhibits or prevents the core from reacting and/or disintegrating until a desired time or event. The one or more surfaces or protective layers are designed to be inert unless exposed to an activation conditions

Methodology Applied
Scientific EffectPassivation:

Data Source

PatentUS12031400B2Fluid activated disintegrating metal system
Publication Date: 2024.07.09 TERVES INC
  • US12031400B2 patent drawing
  • US12031400B2 patent drawing
  • US12031400B2 patent drawing

AI summary

An engineered composite system designed to be passive or inert under one set of conditions, but becomes active when exposed to a second set of conditions. This system can include a dissolving or disintegrating core, and a surface coating that has higher strength or which only dissolves under certain temperature and pH conditions, or in selected fluids. These reactive materials are useful for oil and gas completions and well stimulation processes, enhanced oil and gas recovery operations, as well as in defensive and mining applications requiring high energy density and good mechanical properties, but which can be stored and used for long periods of time without degradation.