Reactive Emulsifier in Nitrile Latex for Dip Molding

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Solution Overview

Problem

Carboxylic acid-modified nitrile-based copolymer latex compositions used in disposable gloves face issues with foam generation during polymerization, leading to defects and a degraded feel due to the use of conventional emulsifiers, which require defoaming agents or maturation processes, and result in emulsifier residues affecting the quality of the final product.

Innovation Solution

Incorporating a reactive emulsifier in the latex composition, which reacts with the monomers during polymerization, reducing foam generation and eliminating the need for defoaming agents or maturation processes, thereby stabilizing the latex and improving the quality of dip molding products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a large amount of conventional emulsifier is used for emulsion polymerization, then the polymerization process can be maintained, but foam generation increases causing defects in gloves

Engineering Contradiction:
Improvepolymerization process stabilityVSAvoidfoam generation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical nature of the emulsifier from conventional adsorption/desorption type to reactive emulsifier that forms chemical bonds with the polymer. This parameter change in emulsifier chemistry reduces foam generation while maintaining polymerization stability, as the reactive emulsifier integrates into the polymer structure rather than remaining as free surfactant that causes foaming.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure where the reactive emulsifier becomes chemically bonded to the nitrile-based copolymer chains. This composite material approach integrates the emulsifier into the polymer matrix, eliminating free emulsifier that would otherwise cause foam generation during dip molding, while the emulsifier continues to perform its polymerization function.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If a defoaming agent is introduced to remove foam, then foam defects are reduced, but the defoaming agent acts as a foreign material causing defects in gloves

Engineering Contradiction:
Improvefoam defectsVSAvoidglove quality
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The patent extracts the need for defoaming agents by fundamentally changing the emulsifier system. Instead of adding a separate defoaming agent to counteract foam, the solution is to use a reactive emulsifier that inherently prevents excessive foam generation through chemical bonding to the polymer, thereby eliminating the need for additional defoaming substances that would act as foreign materials.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent converts the potential harm of emulsifier-related foaming into a benefit by using the reactive emulsifier's chemical bonding capability. The same chemical reactivity that could be seen as a complication becomes the solution, as it anchors the emulsifier to the polymer structure, preventing free emulsifier from causing foam while maintaining polymerization control.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Object-generated harmful factors

If a maturation process is required to eliminate foam, then foam defects are reduced, but processing time increases

Engineering Contradiction:
Improvefoam defectsVSAvoidprocessing time
Core Design Contradiction:
Object-generated harmful factorsVSLoss of time

Solution Approach 1:

The patent applies preliminary action by incorporating the reactive emulsifier into the polymer structure during the polymerization process itself. This prevents foam generation at the source before dip molding occurs, eliminating the need for subsequent maturation processes that would be required with conventional emulsifiers to allow foam to dissipate or be treated.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent skips the maturation step entirely by using a reactive emulsifier system that prevents foam generation in the first place. Instead of allowing foam to form and then requiring time for it to dissipate or be treated during maturation, the reactive emulsifier chemically bonds to the polymer during synthesis, preventing the foam problem from arising and allowing direct progression to dip molding.

Inventive Principle:
Principle #21Skipping (Rushing through)

4Object-generated harmful factors

If conventional emulsifier is not removed sufficiently during leaching, then emulsifier remains in gloves causing foaming and slipping, but thorough removal increases processing complexity

Engineering Contradiction:
Improveemulsifier residue effectsVSAvoidleaching process complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent extracts the emulsifier from the system by chemically bonding it to the polymer structure during synthesis. This eliminates free emulsifier that would otherwise require thorough leaching to remove, as the reactive emulsifier becomes an integral part of the polymer chains and cannot separate or cause foaming and slipping issues during use.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The reactive emulsifier performs self-service by chemically bonding to the polymer during synthesis, effectively anchoring itself to the product it is meant to stabilize. This self-integration eliminates the need for complex leaching processes to remove excess emulsifier, as the emulsifier that remains is chemically bound and cannot migrate to cause surface defects.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of a reactive emulsifier in the carboxylic acid-modified nitrile-based copolymer latex composition significantly reduces foam generation, enhances the quality of the latex, and prevents defects in dip molding products by forming chemical bonds with the copolymer latex, ensuring improved thermal stability and preventing emulsifier outflow, thus simplifying the manufacturing process and maintaining the product's quality.

Implementation Method 1

a reactive emulsifier different from the conventional adsorption/desorption type emulsifier... by adding a reactive emulsifier different from the conventional adsorption/desorption type emulsifier, it is possible to obtain stable latex by using a small amount of reactive emulsifier while not generating a large amount of foam

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentUS9820517B2Carboxylic acid-modified nitrile-based copolymer latex composition, preparation method thereof, and latex composition for dip molding including the same
Publication Date: 2017.11.21 LG CHEM LTD
  • US9820517B2 patent drawing

AI summary

Disclosed is a carboxylic acid-modified nitrile-based copolymer latex composition, including 0.1-10 parts by weight of a reactive emulsifier based on 100 parts by weight of a monomer mixture, wherein the monomer mixture includes 40-88 wt % of a conjugated diene-based monomer, 10-50 wt % of an ethylenically unsaturated nitrile monomer and 0.1-10 wt % of an ethylenically unsaturated acid monomer. Also disclosed are a method of preparing the carboxylic acid-modified nitrile-based copolymer latex composition and a latex composition for dip molding including the same. The carboxylic acid-modified nitrile-based copolymer latex composition reduces generation of foam through the use of a reactive emulsifier different from the conventional adsorption/desorption type emulsifier, thereby preventing degradation of the quality of latex caused by foam. In addition, the carboxylic acid-modified nitrile-based copolymer latex composition avoids a need for introducing a defoaming agent for removing foam or maturation process.