Reactive Fluid Control in Laser Additive Manufacturing

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Solution Overview

Problem

Existing laser additive manufacturing (LAM) techniques face challenges due to the reactivity of powder materials with air, leading to microstructural defects, porosity, and residual stress in fabricated products.

Innovation Solution

The method involves using reactive fluids or fluid mixtures to actively manipulate the surface chemistry of the base material before, during, or after the additive manufacturing process, thereby modifying the surface properties to enhance mechanical and chemical properties of the fabricated products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If reactive fluids are introduced to modify surface chemistry, then mechanical properties and surface resistance are improved, but process complexity increases

Engineering Contradiction:
Improvemechanical strengthVSAvoidprocess complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

A reactive fluid (such as hydrogen-containing gas or reducing atmosphere) is introduced as an intermediary substance between the laser beam and the metal powder particles. This reactive fluid modifies the surface chemistry of the powder particles during the additive manufacturing process, reducing oxide formation and improving mechanical properties without requiring separate post-processing steps.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The chemical composition and reactive properties of the atmosphere surrounding the build chamber are modified by introducing specific gases (e.g., hydrogen, carbon monoxide, or controlled oxygen levels). This parameter change in the atmospheric composition allows for in-situ surface modification of the metal powder during deposition, enhancing mechanical strength and reducing residual stress.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If reactive fluids are used to manipulate surface chemistry, then wear and corrosion resistance are enhanced, but manufacturing cost increases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The reactive fluid treatment is performed preliminarily during the additive manufacturing process itself, rather than as a separate post-processing step. By controlling the atmospheric composition and introducing reactive gases during powder deposition and laser sintering, the surface chemistry is modified in advance, reducing the need for additional coating or treatment operations.

Inventive Principle:
Principle #10Preliminary action

3Object-affected harmful factors

If traditional inert atmosphere handling is used, then safety is improved, but powder production and handling cost increase

Engineering Contradiction:
ImprovesafetyVSAvoidhandling cost
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The atmospheric parameters in the build chamber are dynamically controlled by introducing reactive fluids with specific chemical properties. By adjusting the composition and reactivity of the gas atmosphere, the process achieves both safety (through controlled reactions) and cost-effectiveness (by reducing the need for expensive inert gas handling infrastructure).

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves the mechanical properties of metallic products by reducing residual stress, enhancing wear and corrosion resistance, and increasing mechanical strength, while also reducing the cost of powder production and improving safety handling.

Implementation Method 1

a reactive fluid is contacted with a base material, such as but not limited to a powder, plasma, rod, wire or liquid wherein the reactive fluid modifies the surface of the base material to have a desired chemistry

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

uses an energy beam, for example, an electron beam or electromagnetic radiation such as a laser beam, to sinter or melt a material

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 3

The physical processes associated with laser sintering or laser melting include heat transfer to a powder material

Methodology Applied
Scientific EffectThermal energy transfer: Heating

Implementation Method 4

Fluids including gas mixtures containing hydrogen, carbon monoxide or other gas components that chemically reduce surface oxides

Methodology Applied
Scientific EffectReduction reaction: Reduction

Data Source

PatentUS12305292B2Use of reactive fluids in additive manufacturing and the products made therefrom
Publication Date: 2025.05.20 NIPPON SANSO MATHESON INC
  • US12305292B2 patent drawing
  • US12305292B2 patent drawing
  • US12305292B2 patent drawing

AI summary

The present invention generally relates to methods and apparatuses adapted to perform additive manufacturing (AM) processes and the resulting products made therefrom, and specifically, to AM processes that employ an energy beam to selectively fuse a base material to produce an object. More particularly, the invention relates to methods and systems that use reactive fluids to actively manipulate the surface chemistry of the base material prior to, during and/or after the AM process.