Reactive Mesogen Alignment Layer for Display Afterimage Reduction

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Solution Overview

Problem

Existing display devices face challenges in achieving high reliability due to issues like instant afterimage, surface afterimage, and black afterimage, which are caused by unreacted reactive mesogens leading to unwanted crosslinking during operation.

Innovation Solution

A fabrication method for a display device that includes forming alignment layers with polymerized reactive mesogens, represented by a specific formula, which are used to align liquid crystal molecules, thereby increasing crosslinking reactivity and density, and reducing afterimage effects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If reactive mesogen is used in alignment solution to form alignment layer, then liquid crystal molecules can be aligned in certain direction, but unreacted reactive mesogen remains and causes unwanted crosslinking during operation leading to afterimage effects

Engineering Contradiction:
Improvedisplay reliabilityVSAvoidafterimage effects
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies preliminary action by performing full photopolymerization of the reactive mesogen during the alignment layer formation process. The alignment solution containing reactive mesogen is coated on the substrate, then irradiated with UV light to completely polymerize the reactive mesogen before liquid crystal injection. This ensures no unreacted reactive mesogen remains to cause unwanted crosslinking and afterimage effects during display operation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent converts the potentially harmful unreacted reactive mesogen into a beneficial fully polymerized alignment layer. By controlling the photopolymerization process to achieve complete reaction, the reactive mesogen that could cause harm (unwanted crosslinking, afterimages) is transformed into a stable, crosslinked alignment structure that provides reliable liquid crystal alignment without degradation during operation.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Reliability

If alignment layer is formed by curing alignment solution, then alignment structure is created, but mechanical integrity of alignment layer needs to be enhanced

Engineering Contradiction:
Improvealignment layer stabilityVSAvoidmechanical integrity of alignment layer
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent uses composite materials by combining the reactive mesogen with a polymer matrix in the alignment solution. The reactive mesogen undergoes photopolymerization to form a crosslinked network structure within the polymer matrix, creating a composite alignment layer that enhances mechanical integrity while maintaining the alignment function. This composite structure prevents the alignment layer from deteriorating during display operation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by controlling the photopolymerization process parameters (UV irradiation intensity, exposure time, temperature) to achieve complete crosslinking of the reactive mesogen. By optimizing these parameters, the alignment layer achieves maximum mechanical strength and stability, transforming the soft uncured alignment solution into a rigid, mechanically intact alignment layer that resists deterioration.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enhances the mechanical integrity of alignment layers, decreases afterimage occurrences, and improves display quality by ensuring that the reactive mesogens are fully reacted, resulting in a display device with higher reliability.

Implementation Method 1

curing the alignment solution to form a main alignment layer

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

providing the liquid crystal layer with light to perform reaction of the reactive mesogen to form an alignment forming layer

Methodology Applied
Scientific EffectPhotoreaction: Photopolymerisation

Implementation Method 3

applying heat to the main alignment layer and the liquid crystal layer to elute the reactive mesogen in the main alignment layer to the liquid crystal layer

Methodology Applied
Scientific EffectThermal elution: Diffusion

Data Source

PatentUS9547197B2Fabrication method of display device and display device
Publication Date: 2017.01.17 SAMSUNG DISPLAY CO LTD
  • US9547197B2 patent drawing
  • US9547197B2 patent drawing
  • US9547197B2 patent drawing

AI summary

Provided is a fabrication method of a display device. The method includes providing an alignment solution on at least one of a first substrate and a second substrate, curing the alignment solution to form a main alignment layer, and providing a liquid crystal composition including liquid crystal molecules to form a liquid crystal layer between the first substrate and the second substrate. The alignment solution or the liquid crystal composition includes a reactive mesogen represented by the following Formula 1.