Reactive Sintered Magnetic Articles for Heat Exchange

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Solution Overview

Problem

Current magnetic heat exchange technologies face limitations in scalability and efficiency due to the complexity and cost of producing magnetocaloric materials with optimal Curie temperatures for widespread applications in climate control and refrigeration.

Innovation Solution

Development of a reactive sintered magnetic article with a composition of (La1−aMa)(Fe1−b−cTbYc)13−d, where M, T, and Y are specific elements, allowing for the production of magnetocaloric phases with adjustable Curie temperatures and improved mechanical properties through a simpler manufacturing process, enabling more efficient and cost-effective magnetic refrigeration systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional magnetic heat exchange materials are used, then magnetocaloric effect is achieved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvemagnetocaloric effectVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the chemical composition parameters of the magnetocaloric material by incorporating specific elements (M=Ce, Pr, or Nd; T=Co, Ni, Mn, or Cr; Y=Si, Al, As, Ga, Ge, Sn, or Sb) in controlled amounts to achieve optimal Curie temperature and magnetocaloric effect while simplifying manufacturing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite magnetocaloric material with multiple phases including (La1-aMa)(Fe1-b-cTbYc)13-d and secondary phases, combining different elements to achieve both desired magnetic properties and improved mechanical strength, thereby resolving the contradiction between performance and manufacturing complexity

Inventive Principle:
Principle #40Composite materials

2Productivity

If magnetocaloric materials with optimal Curie temperatures are produced, then refrigeration efficiency improves, but production cost increases

Engineering Contradiction:
Improverefrigeration efficiencyVSAvoidproduction cost
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent adjusts compositional parameters (values of a, b, c, d) to tune the Curie temperature to match specific application requirements, optimizing refrigeration efficiency while controlling production costs through controlled use of rare earth elements

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies different element substitutions at specific lattice positions (La site, Fe site) to locally optimize magnetic properties without requiring expensive bulk material modifications, thereby improving efficiency while controlling overall production cost

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If magnetic heat exchangers are designed for broader applications, then versatility increases, but material performance consistency decreases

Engineering Contradiction:
Improveapplication rangeVSAvoidmaterial performance consistency
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The patent develops a universal magnetocaloric material composition framework (La1-aMa)(Fe1-b-cTbYc)13-d that can be adapted to different applications by adjusting parameters a, b, c, d and selecting different M, T, Y elements, maintaining performance consistency across climate control, refrigeration, and automotive applications

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The invention enables dynamic adjustment of material properties by varying compositional parameters to match different operating temperature ranges and magnetic field conditions, allowing the same base material system to serve multiple applications with consistent performance

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The reactive sintering process results in articles with enhanced mechanical strength, corrosion resistance, and reduced grain size, facilitating the production of magnetocaloric materials suitable for a broader range of applications, including climate control and refrigeration, with increased efficiency and reduced production costs.

Implementation Method 1

reactive sintering the green body to form a magnetocaloric phase

Methodology Applied
Scientific EffectReactive sintering: Sintering

Implementation Method 2

The magnetocaloric effect describes the adiabatic conversion of a magnetically induced entropy change to the evolution or absorption of heat

Methodology Applied
Scientific EffectMagnetocaloric effect: Magnetocaloric Effect

Data Source

PatentUS9895748B2Article for magnetic heat exchange and method of manufacturing the same
Publication Date: 2018.02.20 VACUUMSCHMELZE & GMBH & CO KG
  • US9895748B2 patent drawing
  • US9895748B2 patent drawing
  • US9895748B2 patent drawing

AI summary

Method of manufacturing a reactive sintered magnetic article, a composite article comprising a mantle and at least one core and a laminate article comprising two or more composite articles are provided which each comprise (La1−aMa) (Fe1−b−c−Tb−Y−c)13−dXe, wherein 0≦a≦0.9, 0≦b≦0.2, 0.05≦c≦0.2, −1≦d≦+1, 0≦e≦3.