Reactive Sputtering Inorganic Layer for Fluorine Resin Adhesion

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Solution Overview

Problem

Conventional film formation methods using fluorine-containing resins for touch panels experience reduced adhesion between the stain-proofing layer and the underlying layer over time, leading to potential damage and contamination.

Innovation Solution

A film formation method involving the reactive sputtering technique using water vapor to form an inorganic layer on a substrate, which enhances the adhesion of a fluorine-containing organic layer, with the inorganic layer comprising materials like Si, Al, Ta, Nb, Ti, Zr, Sn, Zn, Mg, and In, and optionally subjected to plasma treatment for improved adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If vacuum deposition technique is used to form fluorine-containing resin film, then film quality is improved, but adhesion between stain-proofing layer and underlying layer deteriorates over time

Engineering Contradiction:
Improvefilm qualityVSAvoidadhesion
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

An inorganic layer is introduced as an intermediary between the substrate and the fluorine-containing resin stain-proofing layer. This intermediate layer, formed by reactive sputtering, provides a surface that enhances adhesion to the organic stain-proofing layer while allowing the vacuum deposition technique to maintain its film quality benefits.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The formation method of the intermediate layer is changed from conventional techniques to reactive sputtering with water vapor. This parameter change in the deposition process creates an inorganic layer with specific surface properties that improve adhesion to the fluorine-containing resin, resolving the adhesion deterioration problem over time.

Inventive Principle:
Principle #35Parameter changes

2Device complexity

If conventional inorganic layer formation is used, then process simplicity is maintained, but adhesion to organic layer deteriorates

Engineering Contradiction:
Improveprocess simplicityVSAvoidadhesion
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The inorganic layer formation process uses reactive sputtering with water vapor as the reactive gas, changing the deposition parameters to create an inorganic layer with enhanced surface properties. This parameter change improves adhesion to the organic stain-proofing layer while maintaining a relatively simple single-step process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves high adhesion between the inorganic and organic layers, maintaining film quality and durability even with repeated use, effectively preventing damage and contamination.

Implementation Method 1

an inorganic layer is formed on the substrate to be processed according to the reactive sputtering technique, while using water vapor as a reactive gas

Methodology Applied
Scientific EffectReactive sputtering: Sputtering

Implementation Method 2

water vapor is introduced into the inorganic layer-forming chamber through the water vapor-introducing means and an electric voltage is applied, through the electric voltage-application means, to thus form a plasma and to thereby form an inorganic layer

Methodology Applied
Scientific EffectPlasma: Plasma

Data Source

PatentUS9903012B2Film formation method and film formation apparatus
Publication Date: 2018.02.27 ULVAC INC
  • US9903012B2 patent drawing
  • US9903012B2 patent drawing
  • US9903012B2 patent drawing

AI summary

A film formation method is one for forming an organic layer comprising a fluorine-containing resin on an inorganic layer (3) formed on a substrate and comprising an inorganic substance. In the method, for the formation of the inorganic layer, a reactive sputtering procedure using water vapor as a reactive gas is carried out to form the inorganic layer on the substrate. Subsequently, the organic layer is formed on the inorganic layer. A film formation device enables the implementation of the film formation method.