Hydroprocessing Reactor Basket for Pressure Drop Reduction

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional hydroprocessing reactors face challenges with high contaminant feedstocks, leading to catalyst deactivation, plugging, and pressure drops due to uneven contaminant distribution, which reduces catalyst life and requires frequent replacements, making it economically unsustainable.

Innovation Solution

The design of a reactor with a basket system that distributes liquid reactants over the entire catalyst bed surface, utilizing a cylindrical basket with particulate matter for contaminant removal, ensuring even flow and extended catalyst life by minimizing plugging and pressure drops, suitable for high contaminant feedstocks like petroleum resids and vegetable oils.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional trickle-bed reactors distribute liquid reactant evenly over the catalyst bed surface, then the reactant distribution is improved, but contaminant concentration at the top region causes plugging and pressure drop

Engineering Contradiction:
Improvereactant distributionVSAvoidcatalyst life
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The reactor is divided into multiple zones: an upper contaminant removal zone with a basket containing particulate material, and a lower catalyst bed zone. This segmentation allows contaminants to be removed in the upper zone before reaching the catalyst bed, preventing plugging and extending catalyst life while maintaining even reactant distribution.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A basket containing particulate material (such as sand, gravel, or ceramic rings) is introduced as an intermediary layer between the liquid reactant distribution system and the catalyst bed. This intermediary layer captures contaminants through filtration and sedimentation, protecting the catalyst bed from direct contact with contaminants and preventing plugging.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If the catalyst bed cross-sectional area is increased to handle high contaminant load, then the processing capacity is improved, but pressure drop increases due to contaminant accumulation

Engineering Contradiction:
Improveprocessing capacityVSAvoidpressure drop
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The reactor is segmented into an upper contaminant removal zone and a lower catalyst bed zone. The upper zone handles the bulk contaminant load through its basket structure, allowing the catalyst bed to operate at higher capacities without experiencing the full brunt of contaminant accumulation, thus maintaining lower pressure drops.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The basket with particulate material acts as an intermediary that intercepts contaminants before they reach the catalyst bed. This protection allows the catalyst bed to maintain higher processing capacity without the pressure drop penalties associated with contaminant accumulation in traditional single-zone reactors.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If frequent catalyst replacement is implemented to maintain performance, then the product quality is improved, but operational costs increase

Engineering Contradiction:
Improveproduct qualityVSAvoidoperational cost
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The basket containing particulate material serves as a protective intermediary layer that filters and removes contaminants before they reach the catalyst bed. This significantly extends catalyst life by preventing deactivation from contaminant exposure, reducing the frequency of catalyst replacement and associated operational costs while maintaining consistent product quality.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

Contaminant removal is performed preliminarily in the upper zone before the liquid reactant reaches the catalyst bed. This preliminary action protects the catalyst from contaminants, extending its operational life and reducing the frequency of replacement, thereby lowering operational costs while maintaining product quality.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This design extends catalyst life, delays plugging, and minimizes pressure drops, allowing for longer process run times and more efficient use of catalysts, reducing the need for frequent replacements and maintaining reactor performance.

Implementation Method 1

the first annular interior space of the basket containing a particulate material for removing contaminants from the feedstock

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Implementation Method 2

particulate material for removing contaminants from the feedstock

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

A distributor assembly is located below and in fluid communication with the inlet for discharging the combined feeds radially outward towards the interior walls of the reactor vessel

Methodology Applied
Scientific EffectRadial flow distribution:

Implementation Method 4

a catalyst bed or layer of support material, or grading, or a combination of these materials, for facilitating the hydroprocessing reaction

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP3983118B1Hydroprocessing reactor to lower pressure drop and extend catalyst life
Publication Date: 2023.10.11 DUKE TECHNOLOGIES LLC
  • EP3983118B1 patent drawingFigure 1
  • EP3983118B1 patent drawingFigure 2
  • EP3983118B1 patent drawingFigure 3

AI summary

A reactor (10, 50, 110, 186) for accommodating high contaminant feedstocks includes a reactor vessel (12, 52, 112) having an inlet (30, 54, 146) for introducing a feedstock containing contaminants (24, 56, 138) into an interior of the reactor vessel (12, 52, 112). A basket (16, 68, 114) is located within the reactor vessel interior and contains a particulate material (20, 78, 126) for removing contaminants from the feedstock to form a purified feedstock that is discharged to a purified feedstock outlet (36, 74, 118). A catalyst (42, 104, 128) is located within the reactor vessel (12, 52, 112) and in fluid communication with the purified feedstock outlet (36, 74, 118) of the basket (16, 68, 114) for contacting the purified feedstock to form a desired product.