Reactor Feed Pipe Cooling to Prevent Saccharide Degradation

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Solution Overview

Problem

The catalytic conversion of saccharides in reactor feed pipes is hindered by degradation at high temperatures, leading to fouling and blocking, resulting in increased running costs and reduced productivity due to reactor shut-downs for cleaning and replacement.

Innovation Solution

Maintaining the saccharide-containing feedstock in the feed pipe below its degradation temperature and cooling a section of the reactor wall at the point of entry to prevent thermal degradation, using cooling liquids or low-pressure steam to manage temperature differences.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the feed pipe temperature is increased to match the reactor temperature, then the catalytic conversion efficiency is improved, but saccharide degradation and fouling occur at the reactor entry point

Engineering Contradiction:
Improvecatalytic conversion efficiencyVSAvoidsaccharide degradation
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The reactor wall is divided into two temperature zones: a cooled section at the feed pipe entry point and a hot bulk reactor zone. This local temperature differentiation allows the feed to be maintained at lower temperature (preventing degradation) while the bulk reactor operates at high temperature (ensuring conversion efficiency).

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The reactor system is segmented into a feed introduction zone with active cooling and a bulk reaction zone at high temperature. This segmentation allows independent temperature control of different functional zones, resolving the contradiction between maintaining low feed temperature and achieving high reaction temperature.

Inventive Principle:
Principle #1Segmentation

2Object-affected harmful factors

If the feed pipe temperature is maintained below degradation temperature, then saccharide degradation is reduced, but the temperature difference between feed and reactor contents increases

Engineering Contradiction:
Improvesaccharide degradationVSAvoidtemperature difference
Core Design Contradiction:
Object-affected harmful factorsVSTemperature

Solution Approach 1:

A cooling medium (liquid or gas) is introduced as an intermediary between the feed pipe and the hot reactor bulk. This intermediary absorbs excess heat at the entry point, preventing direct thermal exposure of the feed to high temperatures while allowing the bulk reactor to maintain high temperature for efficient catalysis.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If reactor shut-downs occur for cleaning and replacement of feed pipes, then fouling is removed, but running costs increase and productivity decreases

Engineering Contradiction:
Improvefeed pipe cleanlinessVSAvoidreactor productivity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

Cooling action is applied preliminarily at the feed pipe entry point before the feed enters the hot reactor zone. This preliminary temperature control prevents degradation and fouling from occurring in the first place, eliminating the need for subsequent cleaning operations and associated productivity losses.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Significantly reduces saccharide degradation at the reactor entry point, minimizing fouling and blocking, thereby reducing downtime and maintenance costs while maintaining reactor efficiency.

Implementation Method 1

a section of the wall of the reactor at the point where the feed pipe enters the reactor is cooled using a cooling liquid, by air cooling

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 2

by using the heat to evaporate water in order to provide low pressure steam

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP3039002B1Process for the conversion of saccharide-containing feedstock
Publication Date: 2018.07.25 SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV
  • EP3039002B1 patent drawingFigure 1

AI summary

The invention provides a process for the catalytic conversion of a saccharide-containing feedstock in a reactor, wherein saccharide-containing feedstock is provided to the reactor as a feed stream through a feed pipe and is contacted with a catalyst system in the reactor, wherein the saccharide-containing feedstock in the feed pipe is maintained at a temperature below the degradation temperature of the saccharide contained therein and a section of the wall of the reactor at the point where the feed pipe enters the reactor is cooled to a temperature below the temperature of the bulk of the reactor and the reactor contents.