Reagentless Biosensor for Amino Acid Detection

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Solution Overview

Problem

Current diagnostic methods for metabolic disorders like hyperammonemia and aminoacidopathies require specialized equipment and hospital settings, making real-time monitoring and management challenging, especially for patients who need frequent assessments.

Innovation Solution

A reagentless biosensor system comprising an electrically conductive support attached to a hydrogel with an immobilized metabolic enzyme, such as phenylalanine dehydrogenase, that allows for real-time detection and quantification of amino acids in bodily fluids without the need for external reagents or stimuli.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If specialized mass spectrometry instrumentation is used in hospital settings, then measurement precision of amino acid levels is improved, but device complexity and ease of operation deteriorate

Engineering Contradiction:
Improveamino acid level detection accuracyVSAvoidinstrumentation complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent extracts the essential detection function from complex hospital-based mass spectrometry systems and implements it in a simplified portable biosensor device. The biosensor uses enzyme electrodes with specific enzymes (e.g., phenylalanine dehydrogenase) immobilized on electroactive supports, eliminating the need for complex mass spectrometry instrumentation while maintaining detection capability for clinical use.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the mechanical and complex analytical system of mass spectrometry with an electrochemical biosensing system. The biosensor uses electrochemical reactions at enzyme-modified electrodes to detect amino acid levels, substituting the complex physical measurement system with a simpler electrochemical approach that can be performed in portable devices.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If hospital-based specialized testing is used, then measurement precision is improved, but loss of time and ease of operation worsen

Engineering Contradiction:
Improveamino acid level detection accuracyVSAvoidtime for patient visits and testing
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent enables patients to perform testing themselves at home using portable biosensor devices, eliminating the need to travel to hospitals for each test. The biosensor is designed for simple operation where patients can collect their own bodily fluid samples and obtain results immediately, performing the testing action in advance and at the point of care rather than waiting for hospital appointments.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent implements a self-service testing system where patients use portable biosensor devices to monitor their own amino acid levels at home. The devices are designed for easy patient operation without requiring specialized hospital staff or equipment, allowing patients to independently perform measurements and track their condition over time.

Inventive Principle:
Principle #25Self-service

3Reliability

If frequent hospital visits for monitoring are required, then reliability of disease management is improved, but loss of time and ease of operation deteriorate

Engineering Contradiction:
Improvedisease management reliabilityVSAvoidtime for frequent patient visits
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent enables continuous monitoring of amino acid levels by allowing patients to perform frequent measurements at home using portable biosensor devices. Instead of discrete hospital visits, patients can continuously track their condition throughout the day and over time, maintaining reliable disease management through ongoing self-monitoring without interruption by travel or scheduling constraints.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables immediate, point-of-care evaluation of amino acid levels in bodily fluids, facilitating timely management and reducing healthcare costs by providing a portable and reliable tool for monitoring and diagnosing metabolic disorders.

Implementation Method 1

the at least one metabolic enzyme is a phenylalanine dehydrogenase from a thermophilic bacterial species... wherein the at least one metabolic enzyme catalyzes oxidation of an amino acid

Methodology Applied
Scientific EffectEnzyme catalysis: Enzyme

Implementation Method 2

the at least one metabolic enzyme catalyzes oxidation of an amino acid resulting in a current on the first electrode

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

the electrically conductive support attached to a hydrogel... wherein the metabolic enzyme is immobilized in the hydrogel

Methodology Applied
Scientific EffectImmobilization in hydrogel: Hydrogel

Implementation Method 4

an amperometer and/or voltmeter operably connected to the at least one electrically conductive support... resulting in a current on the first electrode corresponding to a concentration value

Methodology Applied
Scientific EffectAmperometric detection: Ohmmeter

Data Source

PatentEP2909606B1Device and methods of using device for detection of aminoacidopathies
Publication Date: 2023.12.06 UNIV OF MARYLAND
  • EP2909606B1 patent drawingFigure 1
  • EP2909606B1 patent drawingFigure 2
  • EP2909606B1 patent drawingFigure 3

AI summary

The present invention relates to a biosensor capable of measuring the total concentration of one or a plurality of amino acids with the use of a reagentless system comprising an electrode modified by hydrogel that comprises at least one enzyme that oxidizes at least one substrate that is at least one amino acid. In some embodiments, the biosensor comprises a hydrogel comprising alginate. In some embodiments, the biosensor comprises use of a thermophilic bacterial metabolic enzyme immobilized or attached to the hydrogel.