Rebaudioside A Derivative Flavor Modification via Thermal Acid Hydrolysis

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Solution Overview

Problem

Rebaudioside A, a natural non-caloric sweetener, has flavor and taste characteristics that distinguish it from sugar, and there is a need for novel compounds with more desirable flavor and temporal profiles.

Innovation Solution

A method for preparing rebaudioside A derivative products by heating a rebaudioside A solution with an inorganic acid at 50 to 110°C to obtain a rebaudioside A derivative product with specific chemical formulas, which can be used as sweetening compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If rebaudioside A is used as a sweetener, then it provides non-caloric sweetness with high potency, but it exhibits distinguishable flavor and taste characteristics including bitterness and astringency that differ from sugar

Engineering Contradiction:
Improvesweetening potencyVSAvoidbitterness and astringency
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by heating rebaudioside A at controlled temperatures (50-110°C) for specific time periods to induce chemical transformation. This thermal processing modifies the molecular structure of rebaudioside A, converting it into derivative compounds with improved flavor profiles while maintaining sweetening potency. The temperature and time parameters are carefully optimized to achieve the desired balance between sweetness and reduced bitterness/astringency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs discarding and recovering by selectively removing the bitter and astringent components through controlled degradation. The heating process causes specific chemical bonds to break, discarding the problematic flavor compounds while recovering and preserving the sweetening moieties. This selective degradation allows the final product to retain high sweetening potency while eliminating undesirable taste characteristics.

Inventive Principle:
Principle #34Discarding and recovering

2Object-generated harmful factors

If rebaudioside A is chemically modified to improve flavor profile, then novel compounds with better taste characteristics are obtained, but the complexity of the preparation method increases

Engineering Contradiction:
Improveflavor and taste characteristicsVSAvoidpreparation method complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical separation and purification systems with a simple thermal processing system. Instead of using multiple stages of chromatography, filtration, or centrifugation to remove bitter compounds, the invention uses controlled heating to chemically transform the bitter compounds into desirable products. This substitution dramatically simplifies the preparation methodology while achieving the same flavor improvement goal.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses parameter changes (temperature and time control) as the primary means of chemical modification, avoiding the need for complex reagents, catalysts, or multi-step synthesis procedures. By carefully adjusting the heating parameters, the process achieves selective chemical transformation that improves flavor while maintaining operational simplicity and scalability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces rebaudioside A derivative products with enhanced sweetening potency and flavor profiles, suitable for use as sweeteners, offering intense sweetening potency comparable to or exceeding sucrose at iso-sweetness levels.

Implementation Method 1

heating a rebaudioside A solution with an inorganic acid at about 50 to about 110° C. for a time sufficient to complete the reaction

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

heating a rebaudioside A solution with an inorganic acid at about 50 to about 110° C.

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS9115166B2Rebaudioside A derivative products and methods for making
Publication Date: 2015.08.25 THE COCA COLA CO
  • US9115166B2 patent drawing
  • US9115166B2 patent drawing
  • US9115166B2 patent drawing

AI summary

Exemplary embodiments of this invention encompass a method for degrading rebaudioside A and the rebaudioside A derivative products derived therefrom. In particular, this invention relates to a method for degrading rebaudioside A compositions to obtain rebaudioside A derivative products suitable for use as sweetener compositions.