Receding Contact Angle Measurement via Dynamic Droplet Deposition

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Solution Overview

Problem

Existing methods for measuring receding contact angles are slow and cumbersome, making them unsuitable for rapid and convenient measurement in industrial settings, which is necessary for determining surface properties and controlling processes like coating or treatment.

Innovation Solution

A method and device that rapidly establish a receding contact angle by depositing liquid droplets with controlled energy to expand and then retract, using an imaging sensor to detect geometric characteristics and calculate the contact angle, allowing for quick and accurate measurement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If traditional methods (syringe deposition or Wilhelmy balance) are used to measure receding contact angle, then measurement accuracy is maintained, but measurement time and operational complexity increase significantly

Engineering Contradiction:
Improvereceding contact angle measurement accuracyVSAvoidmeasurement time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent employs periodic droplet deposition to dynamically establish the receding contact angle. Multiple droplets are deposited at controlled intervals, allowing the liquid drop perimeter to advance and retract repeatedly. This periodic action enables the system to capture the receding angle during the retraction phase, significantly reducing measurement time compared to static deposition methods while maintaining accuracy.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent transitions from static liquid drop placement to dynamic droplet deposition. By controlling the timing and energy of each droplet impact, the system creates a dynamic process where the liquid drop perimeter naturally advances and retracts. This dynamic approach allows the receding contact angle to be measured during the retraction phase, reducing the time required compared to traditional static methods.

Inventive Principle:
Principle #15Dynamics

2Reliability

If traditional methods are used to establish receding contact angle, then measurement reliability is maintained, but device complexity and ease of operation deteriorate

Engineering Contradiction:
Improvereceding contact angle measurement reliabilityVSAvoidease of measurement operation
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent implements a self-service measurement system where the liquid drop itself generates the necessary dynamics through periodic droplet deposition. The system automatically captures images during the retraction phase and calculates the receding contact angle without requiring manual intervention or complex external equipment. The liquid drop's own behavior under controlled droplet impact provides the measurement signal, eliminating the need for complex external actuation mechanisms.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces complex mechanical measurement systems (such as the Wilhelmy balance requiring force measurement and delicate balance manipulation) with a simpler imaging-based system. By using high-speed cameras to capture the liquid drop perimeter during retraction and computationally determining the contact angle, the system eliminates complex mechanical components while maintaining measurement reliability and improving ease of operation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Measurement precision

If slow deposition methods are used to form liquid drop, then contact angle measurement accuracy is maintained, but productivity and measurement speed deteriorate

Engineering Contradiction:
Improvecontact angle measurement accuracyVSAvoidmeasurement speed
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent uses periodic droplet deposition to rapidly establish the liquid drop and its receding contact angle. Multiple droplets are deposited at controlled intervals, creating a dynamic process that quickly reaches the measurement phase. This periodic action allows the system to capture the receding angle during the retraction phase, significantly increasing measurement speed while maintaining accuracy through automated image analysis.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent maintains continuous useful action by keeping the liquid drop on the surface throughout the measurement process. Rather than forming the drop and then removing it, the system maintains the drop in place while periodically impacting it with smaller droplets to induce retraction. This continuous presence allows for rapid sequential measurements without the time loss associated with repeated drop placement and removal, significantly improving productivity.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables rapid and convenient determination of receding contact angles, facilitating surface property analysis and process control in industrial settings, improving efficiency and accuracy.

Implementation Method 1

depositing, with a liquid dispenser, a first liquid as liquid droplets along a trajectory toward the surface to form and to impart energy to a liquid drop, wherein each droplet imparts an amount of energy to the liquid drop to increase the volume of the drop

Methodology Applied
Scientific EffectKinetic energy transfer: Impact Force

Implementation Method 2

detecting via the imaging sensor a geometric characteristic of the liquid drop that is related to a reduced contact angle of the liquid drop to the surface

Methodology Applied
Scientific EffectOptical imaging: Photography

Data Source

PatentEP3210004B1Method for measuring surface properties
Publication Date: 2021.03.03 BRIGHTON TECHNOLOGIES LLC
  • EP3210004B1 patent drawingFigure 1~2
  • EP3210004B1 patent drawingFigure 3~6
  • EP3210004B1 patent drawingFigure 7

AI summary

A method and testing apparatus determine receding contact angles of liquids on surfaces by depositing a liquid in a manner whereby the volume of the drop is increased through stepwise addition of smaller drops. Each increment of volume growth causes the perimeter of the drop to advance across the surface. The incremental volume elements impart sufficient energy to the growing drop such that the drop perimeter expands beyond its equilibrium diameter for that volume. The drop perimeter tends to contract between volume additions as the excess energy is dissipated. The method and testing apparatus determine the receding contact angle between the incremental volume additions.