Recycle Content Olefin Production via Integrated Pyrolysis and Cracking

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Solution Overview

Problem

Current recycling processes for waste materials are economically challenging and require expensive sorting, limiting the ability of large-scale production facilities to efficiently process diverse waste materials into recycle content feedstocks for producing non-biodegradable products.

Innovation Solution

A process involving the pyrolysis of recycled waste to produce recycle content pyrolysis oil (r-pyoil), which is then cracked in a furnace to form olefin-containing effluents, utilizing a cracking furnace with specific coil configurations and temperature conditions to enhance recycling efficiency and product yield.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If expensive physical sorting of waste materials is performed to achieve pure single-composition waste volumes, then manufacturing precision of recycle content products is improved, but device complexity and processing cost increase

Engineering Contradiction:
Improvepurity of recycle content productsVSAvoidcomplexity of sorting infrastructure
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent extracts and separates problematic components (heterogeneous materials, contaminants) from the waste stream through pyrolysis processing, allowing the remaining material to be processed as a unified feedstock. This eliminates the need for complex physical sorting infrastructure while achieving consistent product quality through chemical processing.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces mechanical/physical sorting systems with thermal chemical processing. Instead of using mechanical separators, conveyor systems, and manual sorting, the invention uses pyrolysis reactors and cracking furnaces to chemically process mixed waste materials into uniform recycle content products, thereby eliminating complex mechanical sorting infrastructure.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If diverse waste materials are processed together to maximize recycling efficiency, then productivity is improved, but manufacturing precision of products decreases

Engineering Contradiction:
Improverecycling efficiencyVSAvoidproduct composition consistency
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent controls product composition consistency by precisely managing pyrolysis and cracking process parameters (temperature profiles, residence time, oxygen concentration, catalyst conditions). By optimizing these parameters, the system can process diverse waste materials together while maintaining consistent product quality through chemical control rather than physical homogeneity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent treats diverse waste materials as a composite feedstock that is uniformly processed through pyrolysis to create a standardized recycle content oil, which is then cracked to produce consistent olefin products. This approach accepts material diversity in the input while achieving compositional consistency through chemical transformation.

Inventive Principle:
Principle #40Composite materials

3Productivity

If pyrolysis and cracking processes are integrated within production facilities, then productivity is improved, but device complexity increases

Engineering Contradiction:
Improveproduction efficiencyVSAvoidintegration of processing units
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent merges the pyrolysis unit and cracking furnace into an integrated production system where the output of one process feeds directly into the next. This combination eliminates transport steps, intermediate storage, and coordination delays, thereby improving productivity despite the increased complexity of integrating multiple processing units.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent designs the integrated facility to handle multiple waste material types through a single pyrolysis-cracking system, making the facility universally applicable to diverse feedstocks. This multi-functionality improves productivity by consolidating what would otherwise require separate dedicated facilities for different waste streams.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Productivity

If large-scale production facilities process recycle content feedstocks, then productivity is improved, but ease of manufacture decreases

Engineering Contradiction:
Improveproduction volumeVSAvoidprocessing difficulty
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent performs preliminary pyrolysis processing to convert diverse waste materials into a standardized recycle content oil feedstock before the cracking process. This preliminary action simplifies the subsequent cracking operation by providing a consistent feedstock, thereby making large-scale production more manageable and less difficult despite the increased production volume.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the large-scale production of recycle content olefins from diverse waste materials, improving recycling efficiency and environmental impact by integrating pyrolysis and cracking processes within production facilities, thereby reducing the economic and environmental burdens of processing non-biodegradable products.

Implementation Method 1

a pyrolysis unit producing recycle content pyrolysis oil (r-pyoil) and/or recycle content pyrolysis gas (r-pygas)

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 2

cracking a cracker feedstock comprising a recycle content pyrolysis oil composition (r-pyoil) in at least one furnace coil of a cracker furnace

Methodology Applied
Scientific EffectThermal cracking: Thermolysis

Data Source

PatentUS20240218258A1Processes and systems for making recycle content hydrocarbons
Publication Date: 2024.07.04 EXXONMOBIL PRODUCT SOLUTIONS CO
  • US20240218258A1 patent drawing
  • US20240218258A1 patent drawing
  • US20240218258A1 patent drawing

AI summary

Processes and systems for making recycle content hydrocarbons, including olefins, from recycled waste material. Recycle waste material may be pyrolyzed to form recycle content pyrolysis oil composition (r-pyoil), at least a portion of which may then be cracked to form a recycle content olefin composition (r-olefin). In some cases, the pyrolysis and cracking may be carried out in different sections of the same furnace, or in different furnaces in the same cracker facility. Pyrolysis conducted in a furnace may or may not require retrofitting a furnace previously used to crack alkanes to form olefins.