Recycled PET Yarn for Tire Cords With Multi-Stage Drawing

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Solution Overview

Problem

Tire cords produced using recycled polyethylene terephthalate exhibit poor molding processability, impact resistance, heat resistance, and marketability due to property degradation, necessitating a technology that minimizes property deterioration while being environmentally friendly.

Innovation Solution

A method involving the production of recycled polyethylene terephthalate yarn through melting, spinning, and multi-stage drawing using specific godet rolls with controlled draw ratios and speeds, followed by winding, to achieve properties comparable to virgin polyethylene terephthalate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If recycled polyethylene terephthalate is used to produce tire cords, then environmental friendliness is improved, but physical properties such as impact resistance and heat resistance deteriorate

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidimpact resistance and heat resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies parameter changes by precisely controlling the isophthalic acid content (1.0 mol% or less) in the recycled PET chips and optimizing the multi-stage drawing parameters (draw ratios of 1.5-2.45, specific godet roll speeds including 5,500-7,000 m/min for the fourth set). These parameter optimizations resolve the contradiction by maintaining physical properties comparable to virgin PET while using recycled material, thereby achieving both environmental friendliness and mechanical strength.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If recycled polyethylene terephthalate is used to produce tire cords, then environmental friendliness is improved, but molding processability deteriorates

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidmolding processability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent resolves the contradiction between environmental friendliness and molding processability through parameter changes in the drawing process. By controlling the draw ratio within 1.5-2.45 and optimizing the multi-stage drawing conditions (including specific godet roll speeds), the yarn achieves good processability despite using recycled PET with isophthalic acid content of 1.0 mol% or less, thus maintaining both environmental benefits and manufacturing ease.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If recycled polyethylene terephthalate is used to produce tire cords, then environmental friendliness is improved, but appearance deteriorates

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidappearance
Core Design Contradiction:
ReliabilityVSShape

Solution Approach 1:

The patent addresses the contradiction between environmental friendliness and appearance by optimizing the multi-stage drawing parameters. By controlling the draw ratio (1.5-2.45) and implementing specific drawing speeds (5,500-7,000 m/min for the fourth godet roll set), the yarn achieves smooth surface and uniform structure, resolving the appearance issues associated with recycled PET while maintaining environmental benefits.

Inventive Principle:
Principle #35Parameter changes

4Strength

If multi-stage drawing with five or more sets of godet rolls is used, then physical properties such as tenacity and dimensional stability are improved, but device complexity increases

Engineering Contradiction:
Improvetenacity and dimensional stabilityVSAvoidnumber of drawing godet rolls
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies segmentation by dividing the drawing process into five or more distinct stages, each with specific godet roll speed ratios. This segmentation allows progressive orientation and crystallization of the yarn, achieving high tenacity (8.5 g/d or more) and dimensional stability (E-S of 11.0% or less) through controlled multi-stage deformation rather than a single complex operation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent implements dynamics by varying the speeds of different godet roll sets in the multi-stage drawing process. The fourth set of godet rolls operates at 5,500-7,000 m/min, creating dynamic speed differences that control the drawing ratio (1.5-2.45) and enable progressive yarn orientation. This dynamic control achieves superior physical properties while managing device complexity through systematic speed variation.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The recycled polyethylene terephthalate yarn and tire cord exhibit enhanced tenacity, dimensional stability, and fatigue resistance, making them environmentally friendly with properties similar to virgin polyethylene terephthalate.

Implementation Method 1

melting recycled polyethylene terephthalate chips and spinning the melt through a spinning nozzle

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

drawing the spun yarn in multiple stages using an apparatus including five or more sets of drawing godet rolls

Methodology Applied
Scientific EffectDrawing: Deformation

Implementation Method 3

drawing the spun yarn in multiple stages using an apparatus including five or more sets of drawing godet rolls

Methodology Applied
Scientific EffectFriction: Friction

Data Source

PatentEP4636141A1Recycled polyethylene terephthalate yarn and recycled polyethylene terephthalate tire cord
Publication Date: 2025.10.22 HS HYOSUNG ADVANCED MATERIALS CORP
  • EP4636141A1 patent drawingFigure 1
  • EP4636141A1 patent drawing
  • EP4636141A1 patent drawing

AI summary

A method for producing a recycled polyethylene terephthalate yarn according to the present invention includes: melting recycled polyethylene terephthalate chips and spinning the melt through a spinning nozzle, thereby producing a spun yarn; and drawing the spun yarn in multiple stages using an apparatus including five or more sets of drawing godet rolls, followed by winding; wherein the recycled polyethylene terephthalate chips contain isophthalic acid in an amount of 1.0 mol% or less; wherein the drawing is performed at a draw ratio of 1.5 to 2.45; and wherein a fourth set of godet rolls among the five or more sets of drawing godet rolls has a speed of 5,500 m/min to 7,000 m/min. The recycled polyethylene terephthalate yarn produced by the production method has a tenacity of 8.5 g/d or more and a dimensional stability (E-S) of 11.0% or less.