Recycled Polyamide Yarn Blending for Dyeability and Quality Control

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Solution Overview

Problem

Existing methods for recycling polyamide yarns are complex, costly, and energy-intensive, and lack real-time monitoring to ensure quality and homogeneity, particularly in the production of recycled polyamide yarns with high waste polymer content and improved dyeability.

Innovation Solution

A process involving the mixing of industrial polyamide waste with a polyamide rich in amino-end groups using a gravimetric dosing system for melt-spinning, allowing real-time adjustment of the polymer ratio to produce recycled polyamide yarns with enhanced dyeability and elongation capacity, reducing the number of processing steps and environmental impact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If existing recycling methods are used for polyamide yarns, then waste polymer can be recovered, but the process becomes complex, costly, and energy-intensive with no real-time monitoring

Engineering Contradiction:
Improvewaste polymer recoveryVSAvoidprocess complexity
Core Design Contradiction:
Loss of substanceVSDevice complexity

Solution Approach 1:

The invention changes the chemical parameter of the waste polyamide by controlling the concentration of amino-end groups through selective hydrolysis conditions. By adjusting hydrolysis time, temperature, and catalyst concentration, the waste polyamide is transformed to have specific end-group concentrations that enable good dyeability, converting an otherwise unusable material into a high-quality recycled product

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention implements real-time monitoring of amino-end group concentration during the recycling process using titration methods. This feedback mechanism allows continuous adjustment of process parameters to maintain optimal conditions for dyeability and yarn quality, ensuring consistent product performance while simplifying process control

Inventive Principle:
Principle #23Feedback

2Reliability

If high concentration of amino-end groups is achieved in recycled polyamide, then dyeability is improved, but the number of processing steps increases

Engineering Contradiction:
ImprovedyeabilityVSAvoidnumber of processing steps
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The invention merges the hydrolysis step with the melting and spinning process. The waste polyamide is hydrolyzed in situ during the melting phase, combining two previously separate operations (hydrolysis treatment and melt spinning) into a single integrated process flow, thereby achieving high amino-end group concentration without adding extra processing steps

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention performs preliminary hydrolysis of the waste polyamide before spinning by controlling the melting conditions to promote end-group formation. This preliminary chemical modification ensures that the polymer is pre-conditioned with optimal amino-end group concentration before extrusion, guaranteeing good dyeability in the final product

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process results in high-quality recycled polyamide yarns with improved dyeability and elongation properties, comparable to non-recycled yarns, while reducing waste and energy consumption, and ensuring consistent quality through real-time monitoring and adjustment of the polymer blend.

Implementation Method 1

mixing said IPW with said PRA in a gravimetric dosing system

Methodology Applied
Scientific EffectGravimetric dosing:

Implementation Method 2

melt-spinning the mixture

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 3

melt-spinning the mixture

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentUS8366977B2Process of making recycled polyamide yarn
Publication Date: 2013.02.05 NILIT
  • US8366977B2 patent drawing
  • US8366977B2 patent drawing

AI summary

Provided is a process for manufacturing a polyamide yarn exhibiting good dyeability, while utilizing polyamide waste. The recycled polyamide yarn with a high waste polymer content is used for making quality articles by a low cost method, which is further friendly to the preservation of the environment.