Recycled Polyester Prepolymer Processing with Adsorption Bed

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Solution Overview

Problem

Current methods for processing recycled polyester materials in polyester manufacturing processes are inefficient, leading to high energy consumption, equipment costs, and reduced catalyst lifetime due to the need for high combustion temperatures and complex device setups, while also failing to effectively remove semi-volatile impurities, which can result in contamination and degradation of the recycled polyester.

Innovation Solution

A method involving the blending of recycled polyester material with a polyester prepolymer, followed by thermal treatment with a process gas containing organic impurities and controlled oxygen supply, where the process gas is passed through a protective adsorption bed to remove high-boiling substances before catalytic combustion, allowing for lower combustion temperatures and more efficient energy use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high combustion temperatures are used to ensure complete combustion of organic impurities, then combustion efficiency is improved, but energy consumption increases and catalyst lifetime decreases

Engineering Contradiction:
Improvecombustion efficiencyVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent applies preliminary action by removing high-boiling organic substances through adsorption in a protective bed before the combustion step. This pre-removal of refractory compounds prevents catalyst deactivation and allows combustion to proceed at lower temperatures, thereby reducing energy consumption while maintaining combustion efficiency.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces a protective adsorption bed as an intermediary component between the process gas stream and the catalyst bed. This intermediary removes difficult-to-combust substances before they reach the catalyst, protecting the catalyst and enabling lower temperature operation, thus resolving the contradiction between combustion efficiency and energy consumption.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If high combustion temperatures are used to ensure complete combustion of organic impurities, then combustion efficiency is improved, but catalyst lifetime decreases

Engineering Contradiction:
Improvecombustion efficiencyVSAvoidcatalyst lifetime
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The protective adsorption bed performs preliminary removal of high-boiling organic substances that would otherwise cause catalyst deactivation. By eliminating these refractory compounds before combustion, the catalyst operates under milder conditions, extending its service life while maintaining combustion efficiency.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The adsorption bed serves as a protective intermediary that intercepts and removes catalyst-poisoning substances before they can deactivate the catalyst. This intermediary layer allows the catalyst to function at lower temperatures with extended lifetime while maintaining combustion performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If complex device setups with multiple components and pipelines are used to control oxygen supply and measure gas composition, then combustion control precision is improved, but device complexity increases

Engineering Contradiction:
Improvegas composition control precisionVSAvoiddevice complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent extracts and removes high-boiling organic substances from the process gas stream using a protective adsorption bed, eliminating the need for complex measurement and control systems. By physically removing the problematic substances, the system achieves reliable operation without requiring sophisticated sensors and control algorithms.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The adsorption bed acts as a simplifying intermediary that handles the complex task of removing refractory organic substances through adsorption. This physical-chemical intermediary replaces the need for complex measurement and control systems, achieving reliable combustion control with simpler equipment.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If high combustion temperatures are used to combust organic impurities, then complete combustion is achieved, but heat losses increase requiring more insulation material

Engineering Contradiction:
Improvecombustion completenessVSAvoidheat losses
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The protective adsorption bed performs preliminary removal of high-boiling organic substances before combustion. This pre-removal allows the combustion process to operate at lower temperatures, reducing the temperature gradient and minimizing heat losses to the environment, thereby reducing insulation requirements.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The adsorption bed serves as an intermediary that eliminates refractory organic substances, enabling lower temperature combustion. This reduces thermal losses to surroundings and decreases the amount of insulation material needed, resolving the contradiction between combustion completeness and heat losses.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables reliable and continuous processing of recycled polyester materials, reduces energy consumption, and prevents catalyst deactivation, thereby improving the quality and longevity of the recycled polyester products.

Implementation Method 1

the process gas is passed through a protective bed arranged upstream of the heat exchanger for heating the process gas and containing a solid adsorption material which removes high-boiling organic substances or organic substances having a high combustion temperature from the process gas stream

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

introducing the process gas containing organic impurities and optionally an amount of oxygen less than required to completely combust the organic impurities in said process into at least one heat exchanger to heat the process gas

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 3

Combustion of the organic impurities in the process gas in the at least one catalyst bed

Methodology Applied
Scientific EffectCatalytic combustion: Catalysis

Implementation Method 4

a temperature in the range of 100 to 250° C. being set so that the high-boiling substances can condense and be taken up by the adsorption material

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS11839996B2Method and device for processing a mixture of recycled polyester material and a polyester prepolymer from a polyester manufacturing process
Publication Date: 2023.12.12 POLYMETRIX AG
  • US11839996B2 patent drawing
  • US11839996B2 patent drawing

AI summary

A method for processing a mixture of recycled polyester material and a polyester prepolymer from a polyester manufacturing process, wherein a recycled polyester material is mixed with a polyester prepolymer, from a polyester manufacturing process, and treated in a bulk thermal treatment reactor (7) with a process gas which flows in a counter-current or a cross-current flow direction to the flow direction of the mixture. In this process, the process gas, before entering a catalyst vessel (14), is passed through a protective bed (11) containing a solid adsorbent material that removes high-boiling organic substances or organic substances, with a high combustion temperature, from the process gas stream.