Recycled Polyol Foam Quality via Polydispersity Control

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Solution Overview

Problem

Existing methods for producing polyurethane foams using recycled polyols often result in a deterioration of foam quality, especially when high amounts are used, due to varying polydispersity levels.

Innovation Solution

A process for producing polyurethane foams using recycled polyols with a polydispersity of less than 2, preferably less than 1.5, in combination with isocyanate components, catalysts, foam stabilizers, and blowing agents, allowing for high proportions of recycled polyols without compromising foam quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If high amounts of recycled polyols are used in PU foam production, then the proportion of recycled raw materials increases, but the quality of the resulting foams deteriorates

Engineering Contradiction:
Improveproportion of recycled raw materialsVSAvoidquality of foams
Core Design Contradiction:
Loss of substanceVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by controlling the polydispersity of recycled polyols to be less than 2 (preferably less than 1.5). This parameter control enables the use of high proportions of recycled polyols (more than 30%, preferably more than 50%, further preferably more than 70%, in particular more than 95% by weight) while maintaining foam quality comparable to conventional polyols.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If recycled polyols with varying polydispersity levels are used, then the availability of recycled materials increases, but the consistency and quality of foam products deteriorates

Engineering Contradiction:
Improveavailability of recycled materialsVSAvoidconsistency of foam quality
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The patent establishes a specific parameter threshold for polydispersity (D < 2, preferably D < 1.5) to ensure composition stability. This parameter control allows the system to accommodate recycled polyols from various sources while maintaining consistent foam quality, thereby achieving both adaptability and stability.

Inventive Principle:
Principle #35Parameter changes

3Ease of repair

If conventional recycling processes are used to produce recycled polyols, then the recycling of polyurethane waste is enabled, but the quality of resulting polyols varies and compromises foam quality

Engineering Contradiction:
Improverecyclability of polyurethane foamsVSAvoidquality of resulting polyols
Core Design Contradiction:
Ease of repairVSManufacturing precision

Solution Approach 1:

The patent introduces a critical parameter threshold (polydispersity < 2) that transforms the recycling process from producing variable-quality polyols to producing consistent, high-quality recycled polyols. This enables extensive recyclability (more than 95% recycled content) while maintaining manufacturing precision comparable to conventional polyols.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the production of polyurethane foams with quality comparable to those made from conventional polyols, even with high percentages of recycled polyols, thereby increasing the recyclability of polyurethane foams and maintaining foam quality.

Implementation Method 1

one or more catalysts that catalyse the isocyanate-polyol and/or isocyanate-water and/or isocyanate trimerization reactions

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

one or more chemical or physical blowing agents

Methodology Applied
Scientific EffectGas evolution reaction: Chemical Bonding

Data Source

PatentUS20240368332A1Production of PU foams using recycled polyols
Publication Date: 2024.11.07 EVONIK OPERATIONS GMBH
  • US20240368332A1 patent drawing
  • US20240368332A1 patent drawing
  • US20240368332A1 patent drawing

AI summary

A process for producing polyurethane foams is developed by reacting at least one polyol component that includes recycled polyol with at least one isocyanate component, in the presence of one or more catalysts that catalyse the isocyanate-polyol and/or isocyanate-water and/or isocyanate trimerization reactions, at least one foam stabilizer and optionally one or more chemical or physical blowing agents. The polydispersity of the respective recycled polyol is &lt;2. A composition is made that is suitable for production of a polyurethane foam, including at least one polyol component, at least one isocyanate component, a catalyst, a foam stabilizer, a blowing agent and optionally auxiliaries. The at least one polyol component includes a recycled polyol with a polydispersity of &lt;2. A polyurethane foam is made using the above process, and a process is developed for manufacturing goods that include the polyurethane foam.