Recycled Semiconductor on Insulator Substrate Defect Management

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Solution Overview

Problem

The recycling of donor substrates in the SmartCutâ„¢ method for fabricating Semiconductor on Insulator (SeOI) substrates results in defects due to thermal treatments, leading to substrates of lesser quality and limited use, as they can only undergo two SmartCut cycles and may have increased Bulk Micro Defects (BMD) depending on initial properties and temperature gradients.

Innovation Solution

A method where a layer of semiconducting material is formed on the donor substrate by epitaxy before recycling, with a weakened zone created within this layer, and the substrate is chosen to have low oxygen precipitate density and size, allowing for the formation of a high-quality epitaxied layer that is recycled as a receiver substrate for a second SeOI substrate, minimizing thermal treatments and optimizing quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the donor substrate is recycled as receiver substrate after SmartCut cycles, then the number of thermal treatments is reduced, but the substrate still develops Bulk Micro Defects (BMD) due to initial thermal treatments

Engineering Contradiction:
Improvesubstrate qualityVSAvoidBulk Micro Defects
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

A sacrificial layer is formed on the donor substrate before the SmartCut process. This layer is specifically designed to be removed during recycling, taking with it the BMD defects generated during thermal treatments. The sacrificial layer acts as a buffer that protects the underlying substrate from defect propagation in subsequent recycling cycles.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent modifies the physical and chemical parameters of the sacrificial layer (composition, thickness, defect density) to optimize its ability to trap and remove BMD defects. By controlling the layer's parameters, the system achieves effective defect management while maintaining substrate reusability.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If polishing is performed to remove damaged material from recycled substrates, then surface quality is improved, but a significant thickness of material is removed

Engineering Contradiction:
Improvesurface qualityVSAvoidmaterial thickness
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

The sacrificial layer is formed in advance with sufficient thickness to compensate for the material that will be removed during polishing. This preliminary action ensures that after polishing removes the damaged surface layer and BMD defects, enough healthy material remains to maintain the required substrate thickness for subsequent SmartCut cycles.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The sacrificial layer serves as an intermediary between the damaged substrate surface and the healthy bulk material. It provides a controlled zone that can be selectively removed through polishing, separating the harmful surface defects from the useful bulk material underneath.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If the donor substrate undergoes multiple SmartCut cycles, then substrate utilization is maximized, but the density and size of Bulk Micro Defects increase

Engineering Contradiction:
Improvesubstrate utilizationVSAvoidsubstrate quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The sacrificial layer is deliberately designed to be discarded during the recycling process through polishing. By removing this layer that contains accumulated BMD defects, the substrate is recovered in a cleaner state, enabling multiple recycling cycles while maintaining quality standards. The sacrificial layer acts as a disposable component that protects the valuable underlying substrate.

Inventive Principle:
Principle #34Discarding and recovering

Solution Approach 2:

The patent controls the thickness and composition parameters of the sacrificial layer to ensure it can accommodate defect accumulation over multiple cycles. By adjusting these parameters, the system optimizes the balance between substrate reusability and defect management, allowing for controlled multiple recycling operations.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the quality of recycled substrates by reducing defects and enabling the use of substrates for multiple SmartCut cycles, ensuring compliance with electronic component specifications and maintaining high-quality epitaxied semiconducting material, thus improving the overall quality of SeOI substrates.

Implementation Method 1

Oxidation of the donor substrate 10 or receiver substrate 30 to form an oxide layer 20

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

Ion implantation in the donor substrate 10 to form a weakened zone 12

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 3

Bonding of the donor substrate 10 onto the receiver substrate 30, the oxide layer 20 being located at the interface

Methodology Applied
Scientific EffectBonding:

Implementation Method 4

Fracturing the donor substrate 10 in the weakened zone 12 and transfer of a layer 11 from the donor substrate 10 to the receiver substrate 30

Methodology Applied
Scientific EffectFracture: Fracture Mechanics

Implementation Method 5

a layer of semiconducting material is formed on the donor substrate by epitaxy

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS8216917B2Method for fabricating a semiconductor on insulator type substrate
Publication Date: 2012.07.10 SOITEC SA
  • US8216917B2 patent drawing
  • US8216917B2 patent drawing
  • US8216917B2 patent drawing

AI summary

A method for fabricating a substrate of the semiconductor on insulator type by forming an epitaxial layer of semiconducting material on a donor substrate having oxygen precipitates with a density of less than 1010/cm3 or a mean size of less than 500 nm, forming an oxide layer on either a donor or receiver substrate, implanting atomic species in the donor substrate to form a weakened zone in the epitaxial layer, bonding the donor and receiver substrates together, with the oxide layer present at the bonding interface, fracturing the donor substrate in the weakened zone to transfer a layer of the donor substrate to the receiver substrate with the transferred layer including the epitaxial layer, and recycling the remainder of the donor substrate to form a receiver substrate for fabrication of a second semiconductor on insulator type substrate.