Red Mud Catalyst Synthesis Reactor for Carbon Nanotube Production

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional catalysts for producing carbon nanotubes are expensive and inefficient.

Innovation Solution

A method and synthesis reactor using red mud as a catalyst, where the red mud is dried and smashed to create a catalyst, allowing for a circular catalytic reaction with a hydrocarbon source in a fluidized bed reactor, improving catalyst utilization and reducing production costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional catalysts are used for producing carbon nanotubes, then the production can proceed, but the production cost is high and catalyst efficiency is low

Engineering Contradiction:
Improvecatalyst efficiencyVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent replaces expensive conventional catalysts with cheap red mud catalyst derived from aluminum production waste. The catalyst is designed to be used in a fluidized bed system where it can be continuously circulated and regenerated, effectively transforming a disposable expensive catalyst into a reusable inexpensive one, thereby reducing both production cost and improving cost-effectiveness

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the physical and chemical parameters of the catalyst by drying red mud at 101-109°C for 1-4 hours and smashing it through a 200-mesh sieve. These parameter changes activate the catalytic properties of red mud, enabling it to efficiently produce carbon nanotubes despite its low cost, thus resolving the contradiction between catalyst efficiency and production cost

Inventive Principle:
Principle #35Parameter changes

2Productivity

If red mud is used as catalyst in a fluidized bed reactor, then catalyst utilization rate improves, but the reactor structure becomes more complex

Engineering Contradiction:
Improvecatalyst utilization rateVSAvoidreactor structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent implements a continuous circulation system where the catalyst moves continuously between the fluidized bed reactor and the settler. The catalyst is carried by mixed gas into the reactor, performs catalytic function, then settles and is insufflated back into the reactor by fresh mixed gas. This continuous circulation maximizes catalyst utilization rate by ensuring all catalyst particles are repeatedly used, while the systematic design keeps the complexity manageable through functional integration

Inventive Principle:
Principle #20Continuity of useful action

3Quantity of substance

If red mud is dried and smashed to create catalyst, then production cost is reduced, but the processing time increases

Engineering Contradiction:
Improveproduction costVSAvoidcatalyst preparation time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent performs preliminary drying of red mud at 101-109°C for 1-4 hours and smashing through a 200-mesh sieve before the actual carbon nanotube production process. By completing these preparation steps in advance, the catalyst is ready for immediate use in the fluidized bed reactor, and these one-time preparation activities do not significantly impact the continuous production process, thus minimizing time loss while achieving cost reduction

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves high-purity and high-yield carbon nanotubes with reduced raw material consumption and operational complexity, enabling cost-effective continuous production.

Implementation Method 1

allowing the carbon source comprising the hydrocarbon to attach to a surface of the catalyst and thus the hydrocarbon is cracked to yield carbon nanotubes

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

the carbon source comprising the hydrocarbon to attach to a surface of the catalyst and thus the hydrocarbon is cracked to yield carbon nanotubes

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 3

heating a fluidized bed of a main reactor to a temperature of between 600 and 1000° C., and introducing a mixed gas of N2 and a carbon source comprising a hydrocarbon having less than 7 carbon atoms via the air inlet device into the main reactor, where the catalyst is carried by the mixed gas and enters the main reactor

Methodology Applied
Scientific EffectFluidization: Fluidisation

Implementation Method 4

allowing a mixture comprising residue gases and the catalyst to be driven and settle in a settler

Methodology Applied
Scientific EffectSedimentation: Sedimentation

Data Source

PatentUS10081549B2Method and synthesis reactor for producing carbon nanotubes
Publication Date: 2018.09.25 SHANDONG DAZHAN NANO MATERIALS
  • US10081549B2 patent drawing
  • US10081549B2 patent drawing
  • US10081549B2 patent drawing

AI summary

A synthesis reactor for producing carbon nanotubes. The reactor includes a main reactor, a feeder, a settler, an air inlet device, and a product outlet. The main reactor communicates with the settler in the form of a communicating vessel. The feeder communicates with the settler via a catalyst inlet. The air inlet device is disposed under the settler. The wall of the main reactor is provided with a heat exchanger. The product outlet is disposed at the lower part of the main reactor. A method for producing a carbon nanotube, includes: 1) drying red mud for 1 to 4 hour(s) at the temperature of between 101° C. and 109° C.; 2) smashing and sieving the red mud through a 200-mesh sieve to yield a catalyst; and 3) adding the catalyst to a synthesis reactor.