Red Mud Catalyst for CO2 Chemical Reduction

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Solution Overview

Problem

Current methods for reducing carbon dioxide (CO2) into valuable chemicals are not cost-effective and lack simplicity, despite efforts to utilize red mud as a catalyst for CO2 valorization.

Innovation Solution

A method involving a red mud catalyst composition, where a gaseous mixture of CO2 and H2 is reacted in the presence of red mud catalyst particles at specific temperature and pressure conditions to produce a chemical reduction product, including methane, ethane, methanol, and dimethyl ether, using a reactor with various configurations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional catalysts are used for CO2 reduction, then CO2 conversion can be achieved, but the process becomes costly and complex

Engineering Contradiction:
ImproveCO2 conversion efficiencyVSAvoidcatalyst composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs red mud, an inexpensive industrial waste material, as the catalyst instead of costly conventional catalysts. This principle is applied by utilizing a low-cost, readily available material (red mud containing iron oxide and other metal oxides) to perform the catalytic function, thereby reducing the overall process cost while maintaining effective CO2 conversion to value-added chemicals

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent converts red mud, which is typically disposed of as industrial waste requiring landfill space, into a valuable catalyst for CO2 reduction. This transforms an environmental hazard (waste red mud) into a beneficial resource (catalyst), simultaneously addressing waste management issues and enabling cost-effective CO2 valorization

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Ease of manufacture

If simple and cost-effective CO2 reduction methods are implemented, then economic benefits are achieved, but conversion efficiency may be limited

Engineering Contradiction:
Improveprocess simplicity and cost-effectivenessVSAvoidCO2 conversion rate
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent optimizes reaction parameters including temperature (200-800°C), pressure (5-100 bar), and gas composition ratios to maximize CO2 conversion efficiency using the red mud catalyst. By carefully controlling these parameters, the process achieves high conversion rates (producing 20-50 wt% methane, 1-20 wt% ethane, and other value-added products) while maintaining operational simplicity and cost-effectiveness

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively reduces CO2 into valuable hydrocarbons and oxygenates, achieving 10 to 25% conversion with specific product distributions, utilizing red mud as a cost-effective and efficient catalyst for chemical reduction.

Implementation Method 1

reacting at least a portion of the CO2 and the H2 in the gas stream in the presence of the red mud catalyst composition at a temperature of 200 to 800° C., and under a pressure of 5 to 100 bar to form a gaseous product comprising a chemical reduction product of CO2

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

chemically reducing carbon dioxide (CO2) with a red mud catalyst composition

Methodology Applied
Scientific EffectChemical reduction: Reduction

Data Source

PatentUS20240368052A1Method for converting carbon dioxide with red mud catalyst composition
Publication Date: 2024.11.07 KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
  • US20240368052A1 patent drawing
  • US20240368052A1 patent drawing
  • US20240368052A1 patent drawing

AI summary

A method for chemically reducing carbon dioxide (CO2) with a red mud catalyst composition includes introducing a gaseous mixture of CO2 and H2 into a reactor containing red mud catalyst particles of the red mud catalyst composition; and reacting at least a portion of the CO2 and H2 in the gaseous mixture in the presence of the red mud catalyst composition at a temperature of 200 to 800° C., and under a pressure ranging from 5 to 100 bar to form a gaseous product including a chemical reduction product of the CO2. The gaseous product contains 20 to 50 wt. % methane, 1 to 20 wt. % ethane, 0.5 to 10 wt. % propane, 0.01 to 1 wt. % methanol, 1 to 70 wt. % dimethyl ether, and 1 to 50 wt. % carbon monoxide, each wt. % based on a total weight of the gaseous product.