Redistribution Layer Moisture Barrier for Copper Delamination Control

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Solution Overview

Problem

Existing semiconductor packages face challenges in preventing moisture penetration, which can lead to oxidation of copper and delamination issues, particularly in redistribution layers, affecting the reliability and integrity of the package.

Innovation Solution

The implementation of a moisture-resistant layer with a specific composition and surface properties, created through an argon-containing plasma treatment, is applied alternately with polymer layers in the redistribution layer structure to effectively block moisture and prevent delamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polymer layers are used in the redistribution layer structure, then the package structure is formed, but moisture penetration occurs leading to copper oxidation and delamination

Engineering Contradiction:
Improvepackage integrityVSAvoidmoisture penetration
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A moisture-resistant layer is introduced as an intermediary barrier between the polymer layers and the copper conductors. This layer acts as a mediator that blocks moisture penetration while allowing the package structure to maintain its electrical and mechanical functions. The moisture-resistant layer is applied between the polymer layer and the copper conductor surface, creating a protective interface that prevents direct contact between moisture and copper.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The package structure employs a composite material system consisting of multiple layers with different functional properties: polymer layers for structural support and insulation, moisture-resistant layers for barrier protection, and copper layers for electrical conduction. This composite structure combines the advantages of each material while mitigating their individual weaknesses, particularly the moisture sensitivity of copper and the need for structural integrity.

Inventive Principle:
Principle #40Composite materials

2Reliability

If copper is used in the redistribution layer, then electrical conductivity is achieved, but oxidation occurs when moisture penetrates

Engineering Contradiction:
Improveelectrical conductivityVSAvoidcopper oxidation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The moisture-resistant layer serves as a protective intermediary between the copper conductor and the moisture-containing environment. This barrier layer prevents moisture from reaching the copper surface, thereby eliminating the oxidation reaction while maintaining the copper's electrical conductivity. The intermediary layer allows electrical signals to pass through via capacitive coupling or through designated contact points while blocking moisture transport.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The moisture-resistant layer functions as a hydraulic barrier, blocking the transport of moisture molecules through the package structure. By creating a continuous impermeable layer over the copper conductor, it prevents the diffusion of water vapor and liquid moisture to the copper surface, thereby preventing oxidation while allowing the electrical function to persist.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Reliability

If multiple layers are added to prevent moisture, then moisture resistance improves, but device complexity increases

Engineering Contradiction:
Improvemoisture resistanceVSAvoidlayer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The package structure is segmented into distinct functional layers: polymer layers for structural support, moisture-resistant layers for barrier protection, and copper layers for electrical conduction. Each layer is optimized for its specific function, and the segmentation allows for independent optimization of each component while maintaining overall system performance. The moisture-resistant layers are strategically placed only where needed to protect copper conductors.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The moisture-resistant layers are applied locally only in areas where copper conductors are present and require protection, rather than covering the entire package structure uniformly. This localized application reduces the overall complexity and material usage while providing targeted protection where it is most needed. The polymer layers continue to provide general structural support without requiring moisture-resistant modifications in all areas.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enhances the package's resistance to moisture ingress, preventing copper oxidation and delamination, thereby improving the reliability and integrity of the semiconductor package during thermal processes and reliability tests.

Implementation Method 1

created through an argon-containing plasma treatment

Methodology Applied
Scientific EffectPlasma treatment: Plasma

Data Source

PatentUS12183691B2Semiconductor structure and method of forming the same
Publication Date: 2024.12.31 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US12183691B2 patent drawing
  • US12183691B2 patent drawing
  • US12183691B2 patent drawing

AI summary

A semiconductor structure and a method of forming the same are disclosed. A method of forming a semiconductor structure includes the following operations. An insulating layer is formed over a substrate. A metal feature is formed in the insulating layer. An argon-containing plasma treatment is performed to the insulating layer and the metal feature.