Redistribution Structure Etching for Selective Seed Layer Removal

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Solution Overview

Problem

The semiconductor industry faces challenges in forming conductive features with minimal loss and damage during the etching process, particularly in achieving high etching selectivity between seed layers and conductive materials, which affects the precision and reliability of device packaging.

Innovation Solution

The use of an etching solution containing a protective agent with multiple active sites, such as a polyamine, that selectively adsorbs on the conductive material to reduce the etching rate of the conductive material while increasing the etching rate of the seed layer, thereby minimizing the loss and damage of the conductive material and improving etching selectivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional etching solutions are used to remove seed layers, then the seed layer can be etched, but the conductive material suffers from excessive loss and damage due to low etching selectivity

Engineering Contradiction:
Improveetching selectivityVSAvoidconductive material loss
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

A protective agent is introduced as an intermediary substance that selectively adsorbs onto the conductive material surface during etching. This protective agent acts as a mediator that differentially protects the conductive material while allowing the seed layer to be etched away, thereby achieving high etching selectivity and minimizing conductive material loss

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The etching solution parameters are modified by adding a protective agent that changes the chemical environment during etching. This parameter change enables selective adsorption onto the conductive material, altering the etching rate differential between the seed layer and conductive material to achieve superior selectivity

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If etching is performed to remove the seed layer, then the seed layer is removed, but the conductive material surface becomes rough and damaged

Engineering Contradiction:
Improvesurface qualityVSAvoidsurface roughness and damage
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The protective agent serves as a protective intermediary that adsorbs onto the conductive material surface during etching, forming a protective layer that prevents direct contact between the etchant and the conductive material, thereby maintaining surface quality and preventing roughness and damage

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The protective agent provides beforehand cushioning by pre-adsorbing onto the conductive material surface before the etching process fully commences, creating a protective barrier that cushions the conductive material against the harmful effects of the etchant and prevents surface degradation

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the loss and damage of the conductive material, enhances etching selectivity, and improves the surface roughness and reliability of the conductive features, facilitating more precise and reliable device packaging.

Implementation Method 1

an etching solution containing a protective agent with multiple active sites, such as a polyamine, that selectively adsorbs on the conductive material to reduce the etching rate of the conductive material

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12148732B2Package structure and method of fabrcating the same
Publication Date: 2024.11.19 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US12148732B2 patent drawing
  • US12148732B2 patent drawing
  • US12148732B2 patent drawing

AI summary

A method of forming a redistribution structure includes providing a dielectric layer. The dielectric layer is patterned to form a plurality of via openings. A seed layer is formed on the dielectric layer and filling in the plurality of via openings. A patterned conductive layer is formed a on the seed layer, wherein a portion of the seed layer is exposed by the patterned conductive layer. The portion of the seed layer is removed by using an etching solution, thereby forming a plurality of conductive lines and a plurality of vias. During the removing the portion of the seed layer, an etch rate of the patterned conductive layer is less than an etch rate of the seed layer.