Reduced Coenzyme Q10 Particulate Composition Oxidative Stability

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Solution Overview

Problem

Reduced coenzyme Q10 is prone to oxidation, making it challenging to maintain stability during processing and storage, especially in oxygen-rich environments, leading to quality issues and potential health risks from by-products like dehydroascorbic acid and oxalic acid.

Innovation Solution

A particulate composition comprising reduced coenzyme Q10 with a water-soluble excipient matrix, where the oil component is polydispersed and forms a domain with high sphericity, combined with surfactants and sugars, to enhance oxidative stability and oral absorbability, and a method involving packaging in a moisture-proof environment to prevent oxidation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If reduced coenzyme Q10 is used to improve oral absorbability, then oral absorbability is improved, but oxidative stability deteriorates

Engineering Contradiction:
Improveoral absorbabilityVSAvoidoxidative stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent uses ascorbyl palmitate as an intermediary substance that acts as a reducing agent to maintain reduced coenzyme Q10 in its reduced state while protecting it from oxidation. This mediator substance donates electrons to keep coenzyme Q10 reduced without being directly oxidized itself, thus resolving the contradiction between maintaining oral absorbability and preventing oxidation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates an inert environment by using ascorbyl palmitate to establish a reducing atmosphere around the reduced coenzyme Q10. This chemical environment prevents oxygen from oxidizing the reduced coenzyme Q10, effectively creating a protective zone that maintains stability while preserving the reduced form's high oral absorbability

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Stability of the object's composition

If oxidized coenzyme Q10 is used to improve oxidative stability, then oxidative stability is improved, but oral absorbability deteriorates

Engineering Contradiction:
Improveoxidative stabilityVSAvoidoral absorbability
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-reducing coenzyme Q10 to its reduced form and immediately stabilizing it with ascorbyl palmitate before the oxidation can occur. This preliminary reduction and stabilization prevents the need to use oxidized coenzyme Q10, thus maintaining high oral absorbability while achieving oxidative stability through the reducing agent

Inventive Principle:
Principle #10Preliminary action

3Stability of the object's composition

If reducing agents are added to prevent oxidation, then oxidative stability is improved, but harmful by-products are generated

Engineering Contradiction:
Improveoxidative stabilityVSAvoidharmful by-products
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent changes the parameter of the reducing agent from water-soluble forms (which generate harmful by-products like dehydroascorbic acid and oxalic acid) to a lipid-soluble form (ascorbyl palmitate). This parameter change in solubility allows the reducing agent to function in the lipid environment of coenzyme Q10 without generating harmful water-soluble by-products, thus maintaining oxidative stability while avoiding harmful contaminants

Inventive Principle:
Principle #35Parameter changes

4Stability of the object's composition

If complex composition systems are used to stabilize reduced coenzyme Q10, then oxidative stability is improved, but device complexity increases

Engineering Contradiction:
Improveoxidative stabilityVSAvoidcomposition complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent extracts and uses only the essential component needed for stabilization - ascorbyl palmitate - rather than employing complex multi-component systems. By identifying and utilizing this single key reducing agent, the patent achieves oxidative stability while minimizing composition complexity, avoiding the need for multiple stabilizers, antioxidants, and complex formulation systems

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition maintains high oral absorbability and stability of reduced coenzyme Q10, preventing oxidation and ensuring safety by reducing the formation of harmful by-products, thus providing a stable and effective nutritional supplement.

Implementation Method 1

A particulate composition comprising an oil component (A), comprising reduced coenzyme Q10, and a matrix comprising a water-soluble excipient, wherein the oil component (A) is polydispersed forming a domain in the matrix

Methodology Applied
Scientific EffectEmulsion: Emulsion

Implementation Method 2

wherein the water-soluble excipient is a water-soluble polymer, alone or in combination with at least one kind selected from the group consisting of surfactant (C), sugar and a yeast cell wall

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 3

reduced coenzyme Q10 is easily oxidized by molecular oxygen into oxidized coenzyme Q10, and therefore, stabilization of reduced coenzyme Q10 is an important issue

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP2039353B1Reduced coenzyme q10-containing composition and method for producing the same
Publication Date: 2018.12.05 KANEKA CORP
  • EP2039353B1 patent drawingFigure 1
  • EP2039353B1 patent drawingFigure 2
  • EP2039353B1 patent drawingFigure 3

AI summary

The present invention provides a particulate composition wherein an oil component containing reduced coenzyme Q10 is polydispersed forming a domain in a matrix containing a water-soluble excipient, which simultaneously shows high oxidative stability and high oral absorbability, a production method thereof, and a stabilizing method thereof. It also provides a food, food with nutrient function claims, food for specified health uses, dietary supplement, nutritional product, animal drug, drink, feed, pet food, cosmetic, pharmaceutical product, therapeutic drug, prophylactic drug and the like, which contain the composition.