Reducing Power Analysis Preventing Peak Wavelength Shift

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Solution Overview

Problem

The existing reducing power analysis method using a dye reagent with trivalent iron ions and cyanide suffers from peak wavelength shifts in the optical signal, leading to unreliable quantitative analysis results due to interference from components like albumin and methionine in the sample.

Innovation Solution

A reducing power analysis method involving a reduction step at a pH of 2.4 or lower for the dye reagent containing a ferric compound and cyanide, followed by optical measurement at the peak wavelength of the reduced substance, using a strongly acidic pH adjuster to prevent peak wavelength shifts.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If the reducing power analysis is performed using a dye reagent containing trivalent iron ions and cyanide, then the reducing power can be measured, but peak wavelength shift occurs in the optical signal leading to incorrect quantitative analysis

Engineering Contradiction:
Improvereducing power measurementVSAvoidquantitative analysis reliability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent changes the pH parameter of the reaction system to 2.4 or lower (highly acidic condition) to prevent peak wavelength shift. This parameter change stabilizes the optical signal by suppressing interactions between the dye reagent and sample components like albumin and methionine, thereby resolving the contradiction between measurement capability and measurement reliability

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If the optical measurement is performed without controlling pH, then the measurement process is simple, but peak wavelength shift occurs due to sample components like albumin and methionine

Engineering Contradiction:
Improvemeasurement process simplicityVSAvoidoptical signal accuracy
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The patent applies preliminary action by pre-adjusting the pH of the dye reagent to 2.4 or lower before mixing with the sample. This preliminary pH adjustment prevents peak wavelength shift from occurring during the measurement process, maintaining measurement precision while keeping the overall process simple

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach ensures accurate analysis of reducing power by stabilizing the optical signal, reducing errors, and enhancing the reliability of the results in clinical tests and biological samples.

Implementation Method 1

a dye reagent colored blood red by a reaction between trivalent iron ions and a cyanide fades when reduced

Methodology Applied
Scientific EffectRedox reaction: Redox Reactions

Implementation Method 2

a dye reagent colored blood red by a reaction between trivalent iron ions and a cyanide fades when reduced

Methodology Applied
Scientific EffectColor change:

Implementation Method 3

reducing a dye reagent containing a ferric compound and a cyanide at a pH of 2.4 or lower in the presence of a sample

Methodology Applied
Scientific EffectpH control:

Data Source

PatentEP2924433B1Method of analysis of the reducing power of a biological sample
Publication Date: 2020.10.07 ARKRAY INC
  • EP2924433B1 patent drawingFigure 1~2
  • EP2924433B1 patent drawingFigure 3(A)~3(C)
  • EP2924433B1 patent drawingFigure 4~5

AI summary

An object of the present invention is to provide a reducing power analysis method that can prevent peak wavelength shift in a sample. In order to achieve the above object, the reducing power analysis method of the present invention includes: a reduction step of reducing a dye reagent containing a ferric compound and a cyanide at pH conditions of 2.4 or lower in the presence of a sample; and an optical measurement step of optically measuring a peak wavelength of a reduced substance obtained in the reduction step.