Reductive Decolorizing Agent for Oxidative Hair Color Removal

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Solution Overview

Problem

Current reductive decolorization methods for oxidatively colored hair are limited in their ability to restore the hair to its original color effectively, often resulting in undesirable color shifts, damage to the hair structure, and require lengthy exposure times, with existing agents being opaque and difficult to monitor visually.

Innovation Solution

A reductive decolorizing agent is prepared by mixing an acidic, aqueous or aqueous-alcoholic solution with dithionite salts immediately before use, maintaining a pH of less than 5.0 and incorporating a thickener to ensure viscosity and transparency, allowing for effective and visible decolorization of keratin fibers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If oxidative decolorization is used to remove color from hair, then decolorization effectiveness is improved, but hair structure damage and brittleness increase

Engineering Contradiction:
Improvedecolorization effectivenessVSAvoidhair structure damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameter from oxidative to reductive decolorization, using dithionite salts as reducing agents. This fundamental parameter change allows effective color removal while preserving hair structure, as the reducing mechanism breaks down oxidative dye molecules without causing the structural damage associated with oxidative bleaching agents

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the previously harmful effect of strong oxidizing agents that caused hair damage into a beneficial reductive process. By using dithionite salts, the harmful oxidative stress on hair is replaced with a gentle reducing mechanism that achieves decolorization while protecting hair integrity

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Object-affected harmful factors

If reductive decolorization with dithionite salts is used, then hair structure damage is reduced, but decolorization performance is limited and exposure time increases

Engineering Contradiction:
Improvehair structure damageVSAvoiddecolorization performance
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent optimizes the pH parameter of the reductive decolorization system, maintaining it between 4.0 and 6.0. This parameter optimization enhances the decolorization performance of dithionite salts while preserving hair structure, achieving faster and more effective color removal compared to conventional reductive methods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite formulations combining dithionite salts with specific carriers and conditioning agents. This composite approach enhances the decolorization performance by improving agent penetration and effectiveness while simultaneously protecting hair structure through the conditioning components

Inventive Principle:
Principle #40Composite materials

3Ease of operation

If thickening agents are added to reductive decolorizing agents to prevent runoff, then agent retention on hair is improved, but transparency and visual monitoring capability are reduced

Engineering Contradiction:
Improveagent retentionVSAvoidvisual monitoring of decolorization
Core Design Contradiction:
Ease of operationVSDifficulty of detecting and measuring

Solution Approach 1:

The patent carefully controls the concentration and type of thickening agents to achieve optimal viscosity that prevents runoff while maintaining sufficient transparency. This parameter optimization allows the formulation to retain on hair effectively while still enabling visual monitoring of the decolorization progress

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method significantly enhances decolorization performance, reduces hair damage, and allows for direct visual monitoring of the decolorization process, restoring the hair to its original color state while minimizing exposure time and maintaining hair integrity.

Implementation Method 1

Reductive decolorizing agents have less influence on the substrate structure, especially on the structure of keratin-containing fibers. The reductive decolorants hardly decolorize the natural hair color, but only have a reductive effect on the dyes applied by coloring.

Methodology Applied
Scientific EffectReductive decolorization: Reduction

Implementation Method 2

The structure of the substrate can be chemically changed due to the strong oxidizing effect of the oxidizing agent used for decolorization. This is accompanied by an undesirable physical change in the substrate.

Methodology Applied
Scientific EffectpH control:

Implementation Method 3

For this purpose, such agents are thickened accordingly and held at the site of action by the increased viscosity of the agents.

Methodology Applied
Scientific EffectThickening:

Implementation Method 4

For this purpose, it is particularly desirable that the decolorizing preparations applied to the fibers are transparent despite sufficient viscosity so that the color change can be determined immediately.

Methodology Applied
Scientific EffectTransparency:

Data Source

PatentEP2809401B1Reductive color removal
Publication Date: 2017.03.29 HENKEL KGAA
  • EP2809401B1 patent drawing
  • EP2809401B1 patent drawing
  • EP2809401B1 patent drawing

AI summary

The invention relates to an agent for removing color from oxidatively dyed keratin fibers, which is obtained immediately before use by mixing a first aqueous or aqueous-alcoholic preparation (I) containing at least one mineral acid with a second preparation (II) containing at least one dithionite salt, wherein the agent ready for use has a pH value less than 5 and additionally contains a thickening agent.