Reference Electrode Pressing in Solid-State Battery Manufacturing

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Solution Overview

Problem

Current methods for manufacturing all-solid-state batteries face challenges in accurately measuring and analyzing electrochemical properties without disassembly, often resulting in defective batteries due to poor contact between the reference electrode and solid electrolyte, leading to unreliable signal detection and potential short circuits.

Innovation Solution

A manufacturing apparatus and method that compresses solid electrolyte powder with a reference electrode, eliminating the need for conductive paste and ensuring a stable, uniform interface, allowing for reliable electrochemical signal emission without distortion, and enabling the battery to be used without separation from the mold unit.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a reference electrode is inserted into an all-solid-state battery to measure electrochemical properties, then measurement capability is improved, but contact between the reference electrode and solid electrolyte is poor, leading to unreliable signal detection

Engineering Contradiction:
Improveelectrochemical signal detection accuracyVSAvoidsignal detection reliability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent introduces conductive paste as an intermediary material between the reference electrode and the solid electrolyte. This conductive paste fills the gaps and ensures intimate contact between the reference electrode and solid electrolyte, enabling reliable electrochemical signal detection without direct contact between the rigid reference electrode and the solid electrolyte surface.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If conductive paste is used to ensure contact between reference electrode and solid electrolyte, then signal detection reliability is improved, but the battery structure becomes more complex and requires additional materials

Engineering Contradiction:
Improvesignal detection reliabilityVSAvoidbattery structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The conductive paste is applied locally only at the interface between the reference electrode and the solid electrolyte, rather than throughout the entire battery structure. This localized application minimizes the impact on overall battery complexity while ensuring reliable contact specifically where needed for electrochemical measurements.

Inventive Principle:
Principle #3Local quality

3Measurement precision

If the battery is disassembled to measure electrochemical properties, then measurement access is improved, but the battery structure is damaged and lifespan is reduced

Engineering Contradiction:
Improveelectrochemical property measurement accuracyVSAvoidbattery lifespan
Core Design Contradiction:
Measurement precisionVSDuration of action of stationary object

Solution Approach 1:

The reference electrode is inserted and positioned within the battery structure during the manufacturing process, before the battery is sealed and activated. This preliminary placement allows electrochemical measurements to be performed on the complete, functional battery without requiring subsequent disassembly, thereby preserving battery integrity and extending lifespan.

Inventive Principle:
Principle #10Preliminary action

4Ease of operation

If the battery is separated from the mold unit after manufacturing, then the battery can be removed for use, but damage may occur during separation

Engineering Contradiction:
Improvebattery removal capabilityVSAvoidbattery integrity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

Release structures such as hooks or tabs are pre-formed as integral parts of the battery assembly during the molding process. These pre-formed release structures enable easy separation from the mold unit without requiring forceful manual intervention that could damage the battery, thereby maintaining both ease of operation and battery integrity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach provides stable and reliable electrochemical signals, prevents signal distortion, and avoids potential damage during battery separation, ensuring high accuracy in performance evaluation and extended battery lifespan.

Implementation Method 1

a pressing unit which includes a protrusion member corresponding to the first hole, coupled with an upper part of the mold unit, and pressing downwards raw materials of the all-solid-state battery filling the first hole

Methodology Applied
Scientific EffectCompression: Compression

Data Source

PatentUS11909001B2Apparatus for manufacturing all-solid-state battery comprising reference electrode and manufacturing method using same
Publication Date: 2024.02.20 HYUNDAI MOTOR CO LTD
  • US11909001B2 patent drawing
  • US11909001B2 patent drawing
  • US11909001B2 patent drawing

AI summary

An apparatus for manufacturing an all-solid-state battery includes: a mold unit which includes a first hole extending vertically so as to have a shape and a width identical with a shape and a width of the all-solid-state battery, and a second hole extending horizontally so as to horizontally communicate with the first hole; a first pressing unit which includes a first protrusion member corresponding to the first hole, which is coupled with an upper part of the mold unit, and which presses downwards raw materials of the all-solid-state battery filling the first hole, and a second pressing unit which includes a second protrusion member corresponding to the first hole, which is coupled with a lower part of the mold unit, and which presses upwards the raw materials of the all-solid-state battery filling the first hole.