Refractory Composite Composition for Arc-Chute Thermal Shock Resistance

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Solution Overview

Problem

Existing refractory materials, such as reinforced cement-based composites and ceramics, fail to provide simultaneous high mechanical resistance, refractoriness, thermal shock resistance, and machinability for complex shapes in extreme electric operation conditions, particularly in high-voltage applications like arc-chutes.

Innovation Solution

A refractory composite material based on corundum, quartz, and sodium aluminate (NaAl11O17 or Na2O·11Al2O3) is developed, which includes a slurry comprising water-melted alumina, reactive alumina, microsilica, flux oxides, and organic additives, allowing for the creation of items with improved thermal and electric insulation properties through a process involving silicone moulds.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If reinforced cement-based composite materials are used, then mechanical resistance is improved, but resistance to electric arc in high voltage conditions deteriorates

Engineering Contradiction:
Improvemechanical resistanceVSAvoidresistance to electric arc
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent uses a composite material consisting of alumina particles (3-5 mm diameter) embedded in a silicate-based binding matrix. This composite structure combines the high mechanical strength of alumina with the electrical insulation and thermal stability of silicates, creating a material that resists both mechanical stress and electric arc in high voltage conditions.

Inventive Principle:
Principle #40Composite materials

2Reliability

If ceramic materials are used, then resistance to electric arc is improved, but machinability and forming capability deteriorate

Engineering Contradiction:
Improveresistance to electric arcVSAvoidmachinability and forming
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs a silicate-based binding matrix that remains plastic and workable at processing temperatures, allowing the material to be molded into complex shapes using silicone molds. The binding agents maintain formability while the alumina particles provide the required electrical and thermal properties, enabling both complex geometry fabrication and high-voltage resistance.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If materials with high refractoriness are used, then thermal resistance is improved, but resistance to thermal shocks deteriorates

Engineering Contradiction:
ImproverefractorinessVSAvoidresistance to thermal shocks
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent creates a heterogeneous structure where alumina particles of specific size (3-5 mm) are distributed within a silicate matrix. This local arrangement allows different regions to respond differently to thermal stress: the alumina particles provide high-temperature stability while the silicate matrix accommodates thermal expansion differences, enabling the material to withstand rapid temperature changes without cracking.

Inventive Principle:
Principle #3Local quality

4Adaptability or versatility

If complex shapes are manufactured, then adaptability is improved, but manufacturing precision deteriorates

Engineering Contradiction:
Improvecomplex shapesVSAvoiddimensional accuracy
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The patent uses silicone molds as an intermediary tool to form the composite material. The silicone material's flexibility allows it to capture complex geometries with high precision, while the composite's plastic state during processing enables it to take the mold's shape accurately. After curing, the material maintains dimensional stability, ensuring manufacturing precision even for complex forms.

Inventive Principle:
Principle #24Intermediary (Mediator)

Data Source

PatentEP3319922B1Refractory composite material, method for the preparation and use thereof, manufactured items and method for the preparation of said manufactured items.
Publication Date: 2024.11.20 BIGARAN
  • EP3319922B1 patent drawingFigure 1
  • EP3319922B1 patent drawingFigure 2~5
  • EP3319922B1 patent drawing

AI summary

Refractory composite material based on Al2O3 in the form of corundum, SiO2 in the form of quartz and sodium aluminate having the formula NaAl11O17 or Na2O- 11Al2O3, method for preparing the same, use thereof for preparing manufactured items, as well as manufactured items made thereby and use thereof.