Refractory Composition Thermal Shock Resistance

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Solution Overview

Problem

Refractory articles used in high-temperature processes face challenges with corrosion, shock, and deformation, leading to frequent replacement or repair, which results in downtime due to inadequate resistance to these extreme conditions.

Innovation Solution

A refractory composition comprising 50% to 90% chamotte, 5% to 25% mullite, 3% to 20% fused silica, and 3% to 30% aqueous colloidal silica binder, with specific particle size distributions and proportions of chamotte components, providing enhanced shock and creep resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional refractory compositions are used, then the refractory articles can withstand high temperature processes, but they exhibit insufficient resistance to thermal shock and creep, leading to frequent replacement

Engineering Contradiction:
Improveresistance to thermal shock and creepVSAvoiddowntime for replacement or repair
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent changes the chemical composition parameters by incorporating specific amounts of colloidal silica (3-30% by weight), mullite (5-25% by weight), and fused silica (3-20% by weight) to achieve improved thermal shock and creep resistance. This compositional parameter change directly addresses the reliability issue without requiring system redesign.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite refractory material combining multiple components: chamotte (50-90% by weight), mullite, fused silica, and colloidal silica binder. This composite structure leverages the complementary properties of each component to achieve superior thermal shock and creep resistance compared to conventional single-material refractories.

Inventive Principle:
Principle #40Composite materials

2Productivity

If refractory articles are used in extreme high temperature conditions, then they can perform their function, but they suffer from corrosion and deformation, requiring periodic replacement

Engineering Contradiction:
Improvecontinuous operation capabilityVSAvoidcorrosion and deformation at high temperature
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the chemical composition by adding mullite (5-25% by weight) and fused silica (3-20% by weight), which provide enhanced resistance to chemical corrosion and thermal deformation. These parameter changes enable the refractory to withstand extreme conditions without degradation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite refractory composition combines chamotte with mullite and fused silica to create a material that resists both mechanical deformation and chemical corrosion at high temperatures, addressing the harmful factors that limit continuous operation.

Inventive Principle:
Principle #40Composite materials

3Reliability

If refractory articles require periodic replacement or repair, then they can maintain process safety, but it results in downtime for the industrial process

Engineering Contradiction:
Improveservice life of refractoryVSAvoidindustrial process continuity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

By optimizing the composition parameters—specifically the ratios of chamotte, mullite, fused silica, and colloidal silica—the patent extends the service life of refractory articles, reducing the frequency of replacement and maintaining industrial process continuity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies colloidal silica as a binder during manufacturing to pre-strengthen the refractory structure, improving its durability and extending service life before replacement is needed, thereby preventing future downtime.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The refractory composition exhibits excellent high-temperature shock resistance and creep resistance, reducing the need for frequent replacement and minimizing downtime in industrial processes.

Implementation Method 1

about 3% to about 30% by weight of an aqueous colloidal silica binder

Methodology Applied
Scientific EffectColloidal silica binding: Colloid

Implementation Method 2

The refractory composition exhibits excellent high-temperature shock resistance and creep resistance

Methodology Applied
Scientific EffectThermal shock resistance: Thermal Shock

Implementation Method 3

The refractory composition exhibits excellent high-temperature shock resistance and creep resistance

Methodology Applied
Scientific EffectCreep resistance: Creep

Data Source

PatentUS9994486B1Refractory composition resistant to high temperature shock and creep
Publication Date: 2018.06.12 MAGNECO METREL INC

AI summary

A refractory composition yields refractory articles having excellent resistance to high-temperature thermal shock and creep. The refractory composition is based primarily on chamotte having controlled particle sizes, and may also include mullite, fused silica, calcined alumina and microsilica, having controlled particle sizes. The refractory composition includes an aqueous colloidal silica binder that provides excellent castability and binding between the ingredients following drying.