Refrigerant Composition to Suppress Disproportionation Reactions

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Solution Overview

Problem

Refrigerants that undergo disproportionation reactions pose stability issues in air-conditioning systems, leading to potential explosions due to chain reactions, which existing technologies fail to adequately prevent.

Innovation Solution

A composition comprising a refrigerant that includes both refrigerants that undergo disproportionation and those that do not, with a specific formulation where the refrigerant concentration and thermal diffusivity satisfy certain logarithmic relationships to suppress disproportionation reactions, thereby enhancing stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If refrigerants that undergo disproportionation reactions are used, then refrigeration performance is improved, but stability deteriorates due to potential explosions from chain reactions

Engineering Contradiction:
Improverefrigeration performanceVSAvoidstability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent introduces a specific refrigerant composition as an intermediary substance that mediates between the need for high refrigeration performance and the requirement for system stability. The composition containing HFO-1132(E), HFO-1132(Z), and HFO-1123 in controlled proportions acts as a safe alternative that maintains productivity while eliminating the explosion hazard associated with conventional refrigerants that undergo disproportionation reactions

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies parameter changes by precisely controlling the concentration ratios of different HFO components in the refrigerant mixture. By adjusting the proportions of HFO-1132(E), HFO-1132(Z), and HFO-1123 to specific ranges, the system achieves optimal refrigeration performance while maintaining stability below explosion thresholds, thus resolving the contradiction through quantitative parameter optimization

Inventive Principle:
Principle #35Parameter changes

2Productivity

If refrigerant concentration is increased to improve cooling efficiency, then refrigeration performance is improved, but the risk of disproportionation reactions increases

Engineering Contradiction:
Improvecooling efficiencyVSAvoidrisk of disproportionation reactions
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent converts the potential harm of high-concentration refrigerant mixtures into a benefit by selecting HFO components that, when combined in specific proportions, achieve high cooling efficiency while inherently suppressing disproportionation reactions. The specific composition transforms what would be a hazardous high-concentration mixture into a safe and efficient refrigerant system

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Data Source

PatentUS20230242801A1Refrigerant-containing composition
Publication Date: 2023.08.03 DAIKIN INDUSTRIES LTD
  • US20230242801A1 patent drawing
  • US20230242801A1 patent drawing

AI summary

An object of the present disclosure is to provide a composition in which a disproportionation reaction of a refrigerant is suppressed, and in which the refrigerant has excellent stability. Another object of the present disclosure is to provide a composition comprising a refrigerant useful for air-conditioning systems. The composition comprises a refrigerant, wherein the refrigerant comprises a refrigerant that undergoes disproportionation and a refrigerant that does not undergo disproportionation.