Refrigerant Composition with CF3I to Replace R-410A and Reduce GWP

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Solution Overview

Problem

The existing refrigerant R-410A has a high Global Warming Potential (GWP) and is not environmentally friendly, requiring a replacement that maintains performance and compatibility with existing systems while reducing environmental impact.

Innovation Solution

A refrigerant composition comprising at least 97% by weight of difluoromethane (HFC-32), pentafluoroethane (HFC-125), and trifluoroiodomethane (CF3I) is developed, offering excellent heat transfer properties, chemical stability, non-flammability, and low GWP, allowing for direct replacement in R-410A systems without significant system modifications.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If R-410A is used as refrigerant, then heat transfer performance and system efficiency are improved, but Global Warming Potential increases significantly

Engineering Contradiction:
Improveheat transfer performanceVSAvoidGlobal Warming Potential
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the refrigerant by replacing HFC-134a with HFO-1234yf and adjusting the proportions of HFC-32 and HFC-125, thereby reducing GWP while maintaining heat transfer performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite refrigerant mixture combining HFO-1234yf, HFC-32, and HFC-125 in specific proportions to achieve both low GWP and excellent heat transfer properties, replacing the single-component or simple blend approach

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If R-410A is replaced with alternative refrigerants, then environmental impact is reduced, but compatibility with existing systems and operational performance deteriorates

Engineering Contradiction:
Improveenvironmental impactVSAvoidsystem compatibility
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent carefully adjusts the compositional parameters (specific weight percentages of HFC-32, HFC-125, and HFO-1234yf) to match the thermodynamic properties of R-410A, ensuring compatibility with existing compressors and heat exchange systems while achieving lower GWP

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses HFO-1234yf as an intermediary substance that bridges the gap between the performance characteristics of R-410A and the environmental requirements of low-GWP refrigerants, allowing smooth transition without system redesign

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-generated harmful factors

If HFCs are phased down according to F-gas regulation, then environmental compliance is improved, but refrigerant availability and system performance deteriorate

Engineering Contradiction:
Improveenvironmental complianceVSAvoidrefrigerant availability
Core Design Contradiction:
Object-generated harmful factorsVSQuantity of substance

Solution Approach 1:

The patent develops and prepares low-GWP refrigerant compositions in advance of the 2030 phase-down deadline, ensuring continuous availability and preventing performance deterioration by having replacement refrigerants ready before HFC supplies are restricted

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent modifies the refrigerant composition parameters to create alternatives that meet the post-2030 GWP<150 requirements while maintaining adequate quantity and availability for existing and future systems

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The new refrigerant composition achieves a GWP below 427, maintains system efficiency, and ensures non-flammability, making it a suitable drop-in replacement for R-410A in air conditioning and refrigeration systems, reducing environmental impact and operational costs.

Implementation Method 1

evaporating the refrigerant in the vicinity of body or article to be cooled

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

evaporating the refrigerant in the vicinity of body or article to be cooled

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

condensing the refrigerant composition

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 4

heat transfer compositions, methods, and systems

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Data Source

PatentUS20240263059A1Heat transfer compositions, methods, and systems
Publication Date: 2024.08.08 SOLSTICE ADVANCED MATERIALS US INC
  • US20240263059A1 patent drawing
  • US20240263059A1 patent drawing

AI summary

The present invention relates to a refrigerant composition, including difluoromethane (HFC-32), pentafluoroethane (HFC-125), and trifluoroiodomethane (CF3I) for use in a heat exchange system, including air conditioning and refrigeration applications and in particular aspects to the use of such compositions as a replacement of the refrigerant R-410A for heating and cooling applications and to retrofitting heat exchange systems, including systems designed for use with R-410A.