Refrigerating Oil Composition for Trifluoroiodomethane Coloring Control

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The use of trifluoroiodomethane as a refrigerant in refrigerating machines leads to coloring and impurity generation in the refrigerating machine oil, necessitating an improved lubrication solution.

Innovation Solution

A refrigerating machine oil composition comprising an ester-based base oil, alkyl or aryl glycidyl ether epoxy compounds, and a phenol-based antioxidant, with specific mass content, is used to suppress coloring and impurity generation when trifluoroiodomethane is employed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional refrigerating machine oil is used with trifluoroiodomethane refrigerant, then the system can operate, but coloring and impurity generation occur in the oil

Engineering Contradiction:
Improveoil stabilityVSAvoidcoloring and impurities
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the chemical composition parameters of the refrigerating machine oil by incorporating specific additives (ester-based base oil, epoxy compound, and phenol-based antioxidant) in optimized ratios. The epoxy compound content is specifically controlled at 0.7% by mass or more, which fundamentally changes the oil's chemical properties to resist reaction with trifluoroiodomethane, thereby preventing coloring and impurity formation while maintaining operational reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite lubricant system by combining multiple components: ester-based base oil, epoxy compound (alkyl or aryl glycidyl ether), and phenol-based antioxidant. This composite formulation synergistically prevents the harmful reactions between conventional oil and trifluoroiodomethane refrigerant, resolving the contradiction between operational capability and oil degradation

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If trifluoroiodomethane is used as refrigerant, then global warming potential is reduced, but refrigerating machine oil degrades through coloring and impurity formation

Engineering Contradiction:
Improveglobal warming potentialVSAvoidrefrigerating machine oil composition
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The epoxy compound acts as an intermediary substance that protects the refrigerating machine oil from direct harmful interaction with trifluoroiodomethane. The epoxy compound reacts preferentially or forms a protective layer, preventing the refrigerant from causing oil degradation, thus allowing the use of environmentally friendly trifluoroiodomethane while maintaining oil composition stability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By changing the chemical composition parameters of the lubricant system to include specific epoxy compounds and antioxidants, the patent enables compatibility between the environmentally beneficial trifluoroiodomethane refrigerant and the lubricating system, preventing composition degradation while maintaining low global warming potential

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed oil composition effectively reduces coloring and impurity formation, enhancing the performance and stability of refrigerating machines using trifluoroiodomethane as a refrigerant.

Implementation Method 1

a phenol-based antioxidant... capable of suppressing the occurrence of coloring and impurities

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

at least one epoxy compound selected from an alkyl glycidyl ether and an aryl glycidyl ether... when a refrigerant containing trifluoroiodomethane is used

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentEP4130215B1Working fluid composition for refrigerator
Publication Date: 2025.08.13 ENEOS CORP
  • EP4130215B1 patent drawing
  • EP4130215B1 patent drawing
  • EP4130215B1 patent drawing

AI summary

An aspect of the present invention provides a refrigerating machine oil containing an ester-based base oil, at least one epoxy compound selected from an alkyl glycidyl ether and an aryl glycidyl ether, and a phenol-based antioxidant, wherein a content of the epoxy compound is 0.7% by mass or more based on a total amount of the refrigerating machine oil, and the refrigerating machine oil is used with a refrigerant containing trifluoroiodomethane.