Refrigeration Systems and Methods

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Solution Overview

Problem

The refrigeration industry faces challenges in replacing high global warming potential (GWP) refrigerants with safe, efficient, and cost-effective alternatives that meet regulatory requirements, particularly in commercial refrigeration systems, where existing low GWP refrigerants often suffer from safety concerns, high operating costs, and inefficiencies.

Innovation Solution

Development of refrigerant compositions comprising specific blends of HFO-1234ze(E), HFC-134a, and HFO-1224yd(Z) that offer a GWP below 150, non-flammability, and excellent heat transfer properties, while maintaining a capacity greater than 65% of R-134a, and are compatible with lubricants for use in medium and low temperature refrigeration systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If low GWP refrigerants such as carbon dioxide and hydrocarbon refrigerants are used, then the global warming potential is reduced, but system safety and reliability deteriorate due to high flammability

Engineering Contradiction:
Improveglobal warming potentialVSAvoidsystem safety
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent uses composite refrigerant blends combining HFO-1234ze(E) as the base refrigerant with HFC-134 and R1244yd as additives. This composite approach achieves GWP below 150 while maintaining non-flammability (ASHRAE Class A1), resolving the contradiction between low environmental impact and system safety that plagues pure hydrocarbon and CO2 systems.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the compositional parameters of the refrigerant blend, specifically maintaining HFO-1234ze(E) at 63-85% by weight, HFC-134 at 10-35% by weight, and R1244yd at 1-10% by weight. This parameter optimization ensures the blend achieves both low GWP and non-flammable safety characteristics.

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If existing low GWP refrigerant blends are used, then the environmental impact is reduced, but heat transfer performance and system efficiency deteriorate

Engineering Contradiction:
Improveglobal warming potentialVSAvoidsystem energy efficiency
Core Design Contradiction:
Object-generated harmful factorsVSUse of energy by moving object

Solution Approach 1:

The patent optimizes the compositional parameters of the refrigerant blend, specifically maintaining HFO-1234ze(E) at 63-85% by weight, HFC-134 at 10-35% by weight, and R1244yd at 1-10% by weight. This parameter optimization ensures the blend achieves both low GWP and non-flammable safety characteristics.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent enhances the heat transfer properties of the refrigerant blend by selecting specific components with complementary thermodynamic properties. HFO-1234ze(E) provides excellent heat transfer characteristics, while the additives HFC-134 and R1244yd fine-tune the phase change behavior and heat transfer efficiency, ensuring system performance matches or exceeds HFC-134a.

Inventive Principle:
Principle #3Local quality

3Object-generated harmful factors

If refrigerant blends with GWP below 150 are developed, then environmental requirements are met, but non-flammability and heat transfer performance are compromised

Engineering Contradiction:
Improveglobal warming potentialVSAvoidflammability and heat transfer performance
Core Design Contradiction:
Object-generated harmful factorsVSObject-affected harmful factors

Solution Approach 1:

The patent uses composite refrigerant blends combining HFO-1234ze(E) as the base refrigerant with HFC-134 and R1244yd as additives. This composite approach achieves GWP below 150 while maintaining non-flammability (ASHRAE Class A1), resolving the contradiction between low environmental impact and system safety that plagues pure hydrocarbon and CO2 systems.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent enhances the heat transfer properties of the refrigerant blend by selecting specific components with complementary thermodynamic properties. HFO-1234ze(E) provides excellent heat transfer characteristics, while the additives HFC-134 and R1244yd fine-tune the phase change behavior and heat transfer efficiency, ensuring system performance matches or exceeds HFC-134a.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed refrigerant blends achieve a unique combination of low GWP, non-flammability, and high efficiency, reducing environmental impact and operational costs while ensuring safe and reliable performance in commercial refrigeration systems.

Implementation Method 1

evaporating the refrigerant in the evaporator

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

the refrigerant in the low stage refrigeration circuit condenses in the inter-circuit heat exchanger

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

an inter-circuit heat exchanger in which the refrigerant in the low stage refrigeration circuit condenses in the inter-circuit heat exchanger by giving up heat to the refrigerant in the high stage refrigeration circuit

Methodology Applied
Scientific EffectHeat transfer: Heat Exchanger

Data Source

PatentUS20230374362A1Refrigeration Systems and Methods
Publication Date: 2023.11.23 SOLSTICE ADVANCED MATERIALS US INC
  • US20230374362A1 patent drawing
  • US20230374362A1 patent drawing
  • US20230374362A1 patent drawing

AI summary

Disclosed are refrigerants and refrigeration systems, including cascade refrigeration sysemsar comprising: a plurality of refrigeration units, each refrigeration unit containing a first refrigeration circuit, each first refrigeration circuit comprising an evaporator and a heat exchanger; and a second refrigeration circuit; wherein each first circuit heat exchanger is arranged to transfer heat energy between its respective first refrigeration circuit and the second refrigeration circuit.