Rare-Earth Regenerator Particles With Surface Depressions for Helium Flow

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Solution Overview

Problem

Conventional regenerator materials for cryogenic refrigerators face challenges in achieving high-density filling and maximizing the contact surface area with the operating medium gas, such as helium, which affects the refrigerating performance and reliability of superconducting applications like MRI and semiconductor manufacturing.

Innovation Solution

Rare-earth regenerator material particles with specific size and shape characteristics, including an average particle size of 0.01 to 3 mm, a high proportion of particles with an aspect ratio of 2 or less, and depressed portions on their surface, are developed to enhance packing density and contact surface area, utilizing manufacturing methods like the Rotary Disc Process and rotary nozzle processes under controlled conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If spherical particles are used for high-density filling, then packing density is improved, but contact surface area with He gas is reduced

Engineering Contradiction:
Improvepacking densityVSAvoidcontact surface area
Core Design Contradiction:
Quantity of substanceVSArea of stationary object

Solution Approach 1:

The patent applies asymmetry by transitioning from spherical particles to particles with depressed portions on their surfaces. This asymmetric surface modification increases the contact surface area with He gas while maintaining high packing density, as the depressed portions create additional surface area without significantly increasing particle volume or disrupting the close-packing arrangement.

Inventive Principle:
Principle #4Asymmetry

Solution Approach 2:

The depressed portions on particle surfaces create a porous-like surface structure that increases the effective contact area with He gas. This surface porosity allows for greater gas-particle interaction while maintaining the overall particle density and packing efficiency needed for high-performance regenerator operation.

Inventive Principle:
Principle #31Porous materials

2Quantity of substance

If smaller particles are used to fill spaces between larger particles, then packing density is improved, but He gas permeability is reduced

Engineering Contradiction:
Improvepacking densityVSAvoidHe gas permeability
Core Design Contradiction:
Quantity of substanceVSProductivity

Solution Approach 1:

The patent applies local quality by modifying only the surface of each particle with depressed portions, rather than changing the overall particle size distribution. This localized surface modification increases contact area without requiring smaller particles, thereby maintaining the pore spaces and permeability pathways necessary for He gas flow while enhancing the gas-particle contact surface area.

Inventive Principle:
Principle #3Local quality

3Quantity of substance

If particles are filled under high pressure to increase density, then packing density is improved, but particle crushing and clogging occur

Engineering Contradiction:
Improvepacking densityVSAvoidparticle integrity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-forming the depressed portions on particle surfaces during the manufacturing process, before the particles are subjected to filling operations. This preliminary surface structuring allows particles to achieve high packing density through their inherent shape characteristics without requiring excessive filling pressure, thereby preventing particle crushing and maintaining structural integrity.

Inventive Principle:
Principle #10Preliminary action

Data Source

PatentUS10907081B2Rare-earth regenerator material particles, and group of rare-earth regenerator material particles, refrigerator and measuring apparatus using the same, and method for manufacturing the same
Publication Date: 2021.02.02 TOSHIBA MATERIALS CO LTD
  • US10907081B2 patent drawing
  • US10907081B2 patent drawing
  • US10907081B2 patent drawing

AI summary

Provided is a group of rare-earth regenerator material particles having an average particle size of 0.01 to 3 mm, wherein the proportion of particles having a ratio of a long diameter to a short diameter of 2 or less is 90% or more by number, and the proportion of particles having a depressed portion having a length of 1/10 to ½ of a circumferential length on a particle surface is 30% or more by number. By forming the depressed portion on the surface of the regenerator material particles, it is possible to increase permeability of an operating medium gas and a contact surface area with the operating medium gas.