Reinforced Membrane Electrode Assembly for Thin-Layer Durability

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Solution Overview

Problem

Chemical batteries, such as lithium ion batteries and polymer electrolyte fuel cells, face durability issues due to environmental changes like temperature fluctuations, humidity cycles, and pressure variations, leading to layer expansion, contraction, and potential breakage, especially in vehicle-mounted batteries.

Innovation Solution

Incorporating a reinforcing material with high mechanical strength into the layers or between layers of the battery or membrane electrode assembly, such as a high cis-diene polymer with a cis-1,4 bond content of 85% or more, to enhance durability and ion conductivity, which can be used in the electrolyte membrane, catalyst layer, or gas diffusion layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the electrolyte membrane is made thin to reduce resistance, then electrical conductivity is improved, but mechanical strength deteriorates leading to pinholes or membrane breakages

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies composite materials by combining the electrolyte membrane with a reinforcing material having high tensile strength. This composite structure allows the membrane to maintain thin dimensions for low resistance while the reinforcing material provides the necessary mechanical strength to prevent pinholes and breakages during thermal and mechanical cycling.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If the battery operates under environmental changes (temperature, humidity, pressure cycles), then adaptability is improved, but durability deteriorates due to layer expansion, contraction, and breakage

Engineering Contradiction:
Improveenvironmental adaptabilityVSAvoiddurability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent addresses durability under environmental cycling by selecting a reinforcing material whose physical properties (particularly tensile strength and thermal expansion characteristics) are matched to the battery layers. This parameter matching allows the composite structure to withstand repeated thermal expansion and contraction cycles without developing cracks or delamination, thereby maintaining durability despite environmental adaptability requirements.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS11799111B2Battery and membrane electrode assembly
Publication Date: 2023.10.24 ROBERT BOSCH GMBH
  • US11799111B2 patent drawing
  • US11799111B2 patent drawing
  • US11799111B2 patent drawing

AI summary

To provide a battery or a membrane electrode assembly having high durability.A battery (100) having a multilayer structure containing layers of a pair of electrodes (1), the battery (100) including a reinforcing material (20) provided in one or more layers or between layers.