Release Aids with Adjustable Cloud Points for Creping

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Solution Overview

Problem

The paper-making process for tissue and towel products faces challenges in achieving the right balance between adhesion and release of cellulosic fiber webs on the Yankee dryer, affecting crepe quality, softness, and uniformity, due to inadequate control over the adhesion/release balance.

Innovation Solution

The use of release aids containing a mixture of polyethers and hydrophilic polymers, which adjust the cloud point and glass transition temperature, enhancing adhesion, tack, rewetability, and release properties when mixed with an adhesive, allowing for improved control over the creping process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional adhesives are used for creping, then the paper web can be adhered to the Yankee dryer, but the adhesion/release balance cannot be properly controlled, resulting in poor crepe quality

Engineering Contradiction:
Improveadhesion/release balance controlVSAvoidcrepe quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention modifies the adhesive composition by incorporating specific release aids with controlled cloud points and glass transition temperatures. This changes the physical-chemical parameters of the adhesive system, enabling precise control over adhesion and release characteristics during the creping process, thereby resolving the contradiction between reliable adhesion and manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite adhesive system combining base adhesive with specially formulated release aids containing polyethers and hydrophilic polymers. This composite material provides both the necessary adhesion to hold the web on the dryer and the controlled release properties needed for high-quality creping, simultaneously achieving reliable adhesion and manufacturing precision.

Inventive Principle:
Principle #40Composite materials

2Strength

If the adhesion between paper web and Yankee dryer is increased, then the web can be held firmly during drying, but the release becomes difficult causing poor sheet quality or sheet break

Engineering Contradiction:
Improveadhesion strengthVSAvoidsheet break and poor quality
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The invention introduces dynamic control of adhesion strength through temperature-responsive release aids. The adhesive system can maintain strong adhesion at dryer operating temperatures while automatically reducing adhesion strength during the creping phase, preventing sheet break and poor quality without sacrificing initial adhesion strength.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The release aids utilize phase transitions (cloud point and glass transition temperature changes) to dynamically adjust adhesion strength. As temperature and moisture conditions change during processing, the release aids undergo phase transitions that modulate the adhesive properties, enabling strong initial bonding followed by controlled release without damaging the sheet.

Inventive Principle:
Principle #36Phase transitions

3Reliability

If the release aid cloud point is not properly adjusted, then the adhesion/release balance cannot be optimized, but adjusting it requires complex formulation changes

Engineering Contradiction:
Improveadhesion/release balanceVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention systematically adjusts key parameters (cloud point and glass transition temperature) of the release aid formulation to optimize adhesion/release balance. By focusing on these specific controllable parameters rather than complex overall formulation changes, the invention achieves reliable adhesion/release control with manageable formulation adjustments.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides improved control over the creping process, leading to enhanced crepe quality, softness, and uniformity of tissue and towel products by managing the adhesion and release balance effectively.

Implementation Method 1

The release aid, in an aqueous solution that includes water and about 3 vol % of the release aid based on the total volume of the release aid and water, can have a cloud point that is greater than the first temperature and less than the second temperature at a pressure of 100 kPa

Methodology Applied
Scientific EffectCloud point: Phase Change

Implementation Method 2

release aids containing one or more polyethers and one or more hydrophilic polymers, which adjust the cloud point and glass transition temperature, enhancing adhesion, tack, rewetability, and release properties

Methodology Applied
Scientific EffectGlass transition temperature: Phase Change

Implementation Method 3

conductive heat is transferred from the drum

Methodology Applied
Scientific EffectConductive heat transfer: Conduction (thermal)

Implementation Method 4

hydrogen bonds form between the fibers creating a flat and dense web morphology

Methodology Applied
Scientific EffectHydrogen bonding: Chemical Bonding

Data Source

PatentUS9243365B2Release aids with adjustable cloud points for creping processes
Publication Date: 2016.01.26 ECOLAB USA INC
  • US9243365B2 patent drawing
  • US9243365B2 patent drawing
  • US9243365B2 patent drawing

AI summary

Methods for making cellulosic fiber webs using release aids containing one or more polyethers and one or more hydrophilic polymers. In at least one specific embodiment, a release aid having a first temperature can be applied to a drying surface having a second temperature. The second temperature can be greater than the first temperature. The release aid, in an aqueous solution that includes water and about 3 vol % of the release aid based on the total volume of the release aid and water, can have a cloud point greater than the first temperature and less than the second temperature at a pressure of 100 kPa. The method can also include adhering a cellulosic fiber web to the drying surface by contacting the cellulosic fiber web to the drying surface. The method can also include dislodging the cellulosic fiber web from the drying surface.