Remote Plasma Hollow Cathode Discharge for Semiconductor Etching

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Solution Overview

Problem

Conventional semiconductor processing technologies face challenges in achieving high selectivity and minimizing damage to substrates during etching, often resulting in lower quality devices due to lower gas pressures, lower ion and radical densities, and electrode damage.

Innovation Solution

The use of a hollow cathode discharge in combination with a glow discharge in a semiconductor processing system, where a hollow cathode discharge is generated by flowing gas through a conical cavity with a powered electrode and reacting the effluents with the substrate, allowing for higher radical and ion densities and increased selectivity, while reducing electrode damage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If local plasma is used for etching, then trench penetration and structure deformation are improved, but substrate damage increases due to electric arcs

Engineering Contradiction:
Improvetrench penetration and structure deformationVSAvoidsubstrate damage from electric arcs
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The plasma generation is segmented into two separate regions: a remote plasma generation chamber and a substrate processing chamber. The plasma is generated remotely and transported to the substrate region without direct contact, eliminating electric arcs at the substrate interface while maintaining effective etching capability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

A remote plasma source acts as an intermediary, generating reactive species that are transported through a controlled medium to the substrate region. This intermediary approach allows plasma chemistry to be optimized separately from substrate processing conditions, reducing direct plasma-related damage.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If conventional plasma discharge is used, then etching process is achieved, but electrode damage occurs reducing equipment uptime

Engineering Contradiction:
Improveetching process capabilityVSAvoidelectrode damage and equipment uptime
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The plasma generation function is extracted from the substrate processing region and placed in a separate remote chamber. This separation removes the electrode damage issue from the substrate processing system, as electrodes are now isolated in a dedicated plasma generation zone that can be maintained separately.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system transitions from a single-chamber direct plasma approach to a multi-chamber remote plasma approach, adding spatial separation as a new dimension. This allows independent optimization of plasma generation conditions and substrate processing conditions, protecting the substrate region from electrode-related issues.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Quantity of substance

If higher gas pressure is used in hollow cathode discharge, then electron impact ionization rate increases, but discharge stability becomes more challenging

Engineering Contradiction:
Improveelectron impact ionization rateVSAvoiddischarge stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The system utilizes specific pressure ranges (0.1-10 Torr) optimized for hollow cathode discharge operation. By carefully controlling pressure as a key parameter, the system achieves high electron impact ionization rates while maintaining discharge stability through the confining geometry of the hollow cathode structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The hollow cathode structure creates localized regions of high electron density and ionization within its cavity, while the overall chamber maintains stable, controlled conditions. This local quality enhancement allows high ionization rates in specific zones without compromising overall discharge stability.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances etching efficiency, increases process reliability, and reduces substrate damage, leading to improved semiconductor device performance and longer equipment uptime by increasing electron impact ionization and controlling reaction chemistries.

Implementation Method 1

A hollow cathode discharge may be a plasma discharge that increases the electron impact ionization rate at the center of a hollow cathode

Methodology Applied
Scientific EffectElectron impact ionization: Ionisation

Implementation Method 2

Generating a hollow cathode discharge for semiconductor processing, and possibly alternating generation of the hollow cathode discharge with generation of a glow discharge in the same processing chamber

Methodology Applied
Scientific EffectPlasma discharge: Plasma

Implementation Method 3

generation of a glow discharge in the same processing chamber

Methodology Applied
Scientific EffectGlow discharge: Electric Glow Discharge

Data Source

PatentUS9773648B2Dual discharge modes operation for remote plasma
Publication Date: 2017.09.26 APPLIED MATERIALS INC
  • US9773648B2 patent drawing
  • US9773648B2 patent drawing
  • US9773648B2 patent drawing

AI summary

Embodiments of the present technology may include a method of processing a semiconductor substrate. The method may include providing the semiconductor substrate in a processing region. Additionally, the method may include flowing gas through a cavity defined by a powered electrode. The method may further include applying a negative voltage to the powered electrode. Also, the method may include striking a hollow cathode discharge in the cavity to form hollow cathode discharge effluents from the gas. The hollow cathode discharge effluents may then be flowed to the processing region through a plurality of apertures defined by electrically grounded electrode. The method may then include reacting the hollow cathode discharge effluents with the semiconductor substrate in the processing region.